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Quantum mechanics |
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**Waveâparticle duality** is the concept in
quantum mechanics that every
particle or
quantum entity may be described as either a particle or a
wave. It expresses the inability of the
classical concepts "particle" or "wave" to fully describe the behaviour of
quantum-scale objects. As
Albert Einstein wrote:^{
[1]}

It seems as though we must use sometimes the one theory and sometimes the other, while at times we may use either. We are faced with a new kind of difficulty. We have two contradictory pictures of reality; separately neither of them fully explains the phenomena of light, but together they do.

Through the work of
Max Planck,
Albert Einstein,
Louis de Broglie,
Arthur Compton,
Niels Bohr,
Erwin SchrĂ¶dinger and many others, current scientific theory holds that all particles exhibit a wave nature and vice versa.^{
[2]} This phenomenon has been verified not only for elementary particles, but also for compound particles like
atoms and even molecules. For
macroscopic particles, because of their extremely short wavelengths, wave properties usually cannot be detected.^{
[3]}

Although the use of the waveâparticle duality has worked well in physics, the meaning or interpretation has not been satisfactorily resolved; see interpretations of quantum mechanics.

Bohr regarded the "duality
paradox" as a fundamental or metaphysical fact of nature. A given kind of quantum object will exhibit sometimes wave, sometimes particle, character, in respectively different physical settings. He saw such duality as one aspect of the concept of
complementarity.^{
[4]} Bohr regarded renunciation of the cause-effect relation, or complementarity, of the space-time picture, as essential to the quantum mechanical account.^{
[5]}

Werner Heisenberg considered the question further. He saw the duality as present for all quantic entities, but not quite in the usual quantum mechanical account considered by Bohr. He saw it in what is called
second quantization, which generates an entirely new concept of fields that exist in ordinary space-time, causality still being visualizable. Classical field values (e.g. the electric and magnetic field strengths of
Maxwell) are replaced by an entirely new kind of field value, as considered in
quantum field theory. Turning the reasoning around, ordinary quantum mechanics can be deduced as a specialized consequence of quantum field theory.^{
[6]}^{
[7]}

Democritus (5th century BC) argued that all things in the universe, including
light, are composed of indivisible sub-components.^{
[8]}
Euclid (4thâ3rd century BC) gives treatises on light propagation, states the principle of shortest trajectory of light, including multiple reflections on mirrors, including spherical, while
Plutarch (1stâ2nd century AD) describes multiple reflections on spherical mirrors discussing the creation of larger or smaller images, real or imaginary, including the case of
chirality of the images. At the beginning of the 11th century, the Arabic scientist
Ibn al-Haytham wrote the first comprehensive *
Book of Optics* describing
reflection,
refraction, and the operation of a pinhole lens via rays of light traveling from the point of emission to the eye. He asserted that these rays were composed of particles of light. In 1630,
RenĂ© Descartes popularized the opposing wave description in his treatise on light,
The World, showing that the behaviour of light could be re-created by modeling wave-like disturbances in a universal medium i.e.
luminiferous aether. Beginning in 1670 and progressing over three decades,
Isaac Newton developed and championed his
corpuscular theory, arguing that the perfectly straight lines of reflection demonstrated light's particle nature, only particles could travel in such straight lines. He explained refraction by positing that particles of light accelerated laterally upon entering a denser medium. Around the same time, Newton's contemporaries
Robert Hooke and
Christiaan Huygens, and later
Augustin-Jean Fresnel, mathematically refined the wave viewpoint, showing that if light traveled at different speeds in different media, refraction could be easily explained as the medium-dependent propagation of light waves. The resulting
HuygensâFresnel principle was extremely successful at reproducing light's behaviour and was consistent with
Thomas Young's discovery of
wave interference of light by his
double-slit experiment in 1801.^{
[9]} The wave view did not immediately displace the ray and particle view, but began to dominate scientific thinking about light in the mid 19th century, since it could explain polarization phenomena that the alternatives could not.^{
[10]}

James Clerk Maxwell discovered that he could apply his previously discovered Maxwell's equations, along with a slight modification to describe self-propagating waves of oscillating electric and magnetic fields. It quickly became apparent that visible light, ultraviolet light, and infrared light were all electromagnetic waves of differing frequency.

Animation showing the waveâparticle duality with a double-slit experiment and effect of an observer. Increase size to see explanations in the video itself. See also a quiz based on this animation.

Particle impacts make visible the interference pattern of waves.

A quantum particle is represented by a wave packet.

In 1901, Max Planck published an analysis that succeeded in reproducing the observed spectrum of light emitted by a glowing object. To accomplish this, Planck had to make a mathematical assumption of quantized energy of the oscillators, i.e. atoms of the black body that emit radiation. Einstein later proposed that electromagnetic radiation itself is quantized, not the energy of radiating atoms.

Black-body radiation, the emission of electromagnetic energy due to an object's heat, could not be explained from classical arguments alone. The equipartition theorem of classical mechanics, the basis of all classical thermodynamic theories, stated that an object's energy is partitioned equally among the object's vibrational modes. But applying the same reasoning to the electromagnetic emission of such a thermal object was not so successful. That thermal objects emit light had been long known. Since light was known to be waves of electromagnetism, physicists hoped to describe this emission via classical laws. This became known as the black body problem. Since the equipartition theorem worked so well in describing the vibrational modes of the thermal object itself, it was natural to assume that it would perform equally well in describing the radiative emission of such objects. But a problem quickly arose if each mode received an equal partition of energy, the short wavelength modes would consume all the energy. This became clear when plotting the RayleighâJeans law, which, while correctly predicting the intensity of long wavelength emissions, predicted infinite total energy as the intensity diverges to infinity for short wavelengths. This became known as the ultraviolet catastrophe.

In 1900, Max Planck hypothesized that the frequency of light emitted by the black body depended on the frequency of the oscillator that emitted it, and the energy of these oscillators increased linearly with frequency (according *E* = *hf* where *h* is Planck's constant and *f* is the frequency). This was not an unsound proposal considering that macroscopic oscillators operate similarly when studying five
simple harmonic oscillators of equal amplitude but different frequency, the oscillator with the highest frequency possesses the highest energy (though this relationship is not linear like Planck's). By demanding that high-frequency light must be emitted by an oscillator of equal frequency, and further requiring that this oscillator occupy higher energy than one of a lesser frequency, Planck avoided any catastrophe, giving an equal partition to high-frequency oscillators produced successively fewer oscillators and less emitted light. And as in the
MaxwellâBoltzmann distribution, the low-frequency, low-energy oscillators were suppressed by the onslaught of thermal jiggling from higher energy oscillators, which necessarily increased their energy and frequency.

The most revolutionary aspect of Planck's treatment of the black body is that it inherently relies on an integer number of oscillators in
thermal equilibrium with the electromagnetic field. These oscillators give their entire energy to the electromagnetic field, creating a quantum of light, as often as they are excited by the electromagnetic field, absorbing a quantum of light and beginning to oscillate at the corresponding frequency. Planck had intentionally created an atomic theory of the black body, but had unintentionally generated an atomic theory of light, where the black body never generates quanta of light at a given frequency with an energy less than *hf*. However, once realizing that he had quantized the electromagnetic field, he denounced particles of light as a limitation of his approximation, not a property of reality.

While Planck had solved the ultraviolet catastrophe by using atoms and a quantized electromagnetic field, most contemporary physicists agreed that Planck's "light quanta" represented only flaws in his model. A more-complete derivation of black-body radiation would yield a fully continuous and "wave-like" electromagnetic field with no quantization. However, in 1905 Albert Einstein took Planck's black body model to produce his solution to another outstanding problem of the day: the photoelectric effect, wherein electrons are emitted from atoms when they absorb energy from light. Since their existence was theorized eight years previously, phenomena had been studied with the electron model in mind in physics laboratories worldwide.

In 1902,
Philipp Lenard discovered that the energy of these ejected electrons did not depend on the intensity of the incoming light, but instead on its frequency. So if one shines a little low-frequency light upon a metal, a few low energy electrons are ejected. If one now shines a very intense beam of low-frequency light upon the same metal, a whole slew of electrons are ejected; however they possess the same low energy, there are merely more of them. The more light there is, the more electrons are ejected. Whereas in order to get high energy electrons, one must illuminate the metal with high-frequency light. Like blackbody radiation, this was at odds with a theory invoking continuous transfer of energy between radiation and matter. However, it can still be explained using a fully classical description of light, as long as matter is quantum mechanical in nature.^{
[11]}

If one used Planck's energy quanta, and demanded that electromagnetic radiation at a given frequency could only transfer energy to matter in integer multiples of an energy quantum *hf*, then the photoelectric effect could be explained very simply. Low-frequency light only ejects low-energy electrons because each electron is excited by the absorption of a single photon. Increasing the intensity of the low-frequency light (increasing the number of photons) only increases the number of excited electrons, not their energy, because the energy of each photon remains low. Only by increasing the frequency of the light, and thus increasing the energy of the photons, can one eject electrons with higher energy. Thus, using Planck's constant *h* to determine the energy of the photons based upon their frequency, the energy of ejected electrons should also increase linearly with frequency, the gradient of the line being Planck's constant. These results were not confirmed until 1915, when
Robert Andrews Millikan produced experimental results in perfect accord with Einstein's predictions.

While energy of ejected electrons reflected Planck's constant, the existence of photons was not explicitly proven until the discovery of the
photon antibunching effect. This refers to the observation that once a single emitter (an atom, molecule, solid state emitter, etc.) radiates a detectable light signal, it cannot immediately release a second signal until after the emitter has been re-excited. This leads to a statistically quantifiable time delay between light emissions, so detection of multiple signals becomes increasingly unlikely as the observation time dips under the excited-state lifetime of the emitter.^{
[12]} The effect can be demonstrated in an undergraduate-level lab.^{
[13]}

This phenomenon could only be explained via photons. Einstein's "light quanta" would not be called photons until 1925, but even in 1905 they represented the quintessential example of waveâparticle duality. Electromagnetic radiation propagates following linear wave equations, but can only be emitted or absorbed as discrete elements, thus acting as a wave and a particle simultaneously.

In 1905, Albert Einstein provided an explanation of the photoelectric effect, an experiment that the wave theory of light failed to explain. He did so by postulating the existence of photons, quanta of light energy with particulate qualities.

In the photoelectric effect, it was observed that shining a light on certain metals would lead to an electric current in a circuit. Presumably, the light was knocking electrons out of the metal, causing current to flow. However, using the case of potassium as an example, it was also observed that while a dim blue light was enough to cause a current, even the strongest, brightest red light available with the technology of the time caused no current at all. According to the classical theory of light and matter, the strength or amplitude of a light wave was in proportion to its brightness: a bright light should have been easily strong enough to create a large current. Yet, oddly, this was not so.

Einstein explained this enigma by
postulating that electrons can receive energy from an electromagnetic field only in discrete units (quanta or photons): an amount of
energy *E* that was related to the
frequency *f* of the light by

where *h* is
Planck's constant (6.626 Ă 10^{â34} Js). Only photons of a high enough frequency (above a certain *threshold* value) could knock an electron free. For example, photons of blue light had sufficient energy to free an electron from the metal, but photons of red light did not. One photon of light above the threshold frequency could release only one electron; the higher the frequency of a photon, the higher the kinetic energy of the emitted electron, but no amount of light below the threshold frequency could release an electron. To violate this law would require extremely high-intensity lasers that had not yet been invented. Intensity-dependent phenomena have now been studied in detail with such lasers.^{
[14]}

Einstein was awarded the Nobel Prize in Physics in 1921 for his discovery of the law of the photoelectric effect.

In 1924,
Louis-Victor de Broglie formulated the
de Broglie hypothesis, claiming that all matter has a wave-like nature.^{
[15]}^{
[16]} He related
wavelength and
momentum:

This is a generalization of Einstein's equation above, since the momentum of a photon is given by and the wavelength (in a vacuum) by , where *c* is the
speed of light in vacuum.

De Broglie's formula was confirmed three years later for electrons with the observation of electron diffraction, as it had been observed with X-rays, in two independent experiments. At the University of Aberdeen, George Paget Thomson passed a beam of electrons through a thin metal film and observed the predicted interference patterns. At Bell Labs, Clinton Joseph Davisson and Lester Halbert Germer guided the electron beam through a crystalline grid in their experiment popularly known as DavissonâGermer experiment.

De Broglie was awarded the Nobel Prize for Physics in 1929 for his hypothesis. Thomson and Davisson shared the Nobel Prize for Physics in 1937 for their experimental work.

De Broglie's proposal also predicts particle interferometry. In particular, single-particle interferometry has become a classic for its clarity in expressing the central puzzles of quantum mechanics. Because it demonstrates the fundamental limitation of the ability of the observer to predict experimental results,
Richard Feynman called it "a phenomenon which is impossible [âŠ] to explain in any
classical way, and which has in it the heart of quantum mechanics. In reality, it contains the only mystery [of quantum mechanics].^{
[17]} In 1974, the Italian physicists Pier Giorgio Merli, Gian Franco Missiroli, and
Giulio Pozzi performed the first experiment of single particle interferometry using electrons and a biprism (instead of slits), showing that each electron interferes with itself as predicted by quantum theory.^{
[18]}^{
[19]} In 2018, single particle interference has been first demonstrated for antimatter in the
Positron Laboratory (L-NESS) of Rafael Ferragut in
Como (
Italy), by a group led by Marco Giammarchi.^{
[20]}

In his work on formulating quantum mechanics, Werner Heisenberg postulated his uncertainty principle, which states:

where

- here indicates standard deviation, a measure of spread or uncertainty;
- x and p are a particle's position and linear momentum respectively.
*is the reduced Planck's constant (Planck's constant divided by 2).*

Heisenberg originally explained this as a consequence of the process of measuring: Measuring position accurately would disturb momentum and vice versa, offering an example (the "gamma-ray microscope") that depended crucially on the de Broglie hypothesis. The thought is now, however, that this only partly explains the phenomenon, but that the uncertainty also exists in the particle itself, even before the measurement is made.

In fact, the modern explanation of the uncertainty principle, extending the Copenhagen interpretation first put forward by Bohr and Heisenberg, depends even more centrally on the wave nature of a particle. Just as it is nonsensical to discuss the precise location of a wave on a string, particles do not have perfectly precise positions; likewise, just as it is nonsensical to discuss the wavelength of a "pulse" wave traveling down a string, particles do not have perfectly precise momenta that correspond to the inverse of wavelength. Moreover, when position is relatively well defined, the wave is pulse-like and has a very ill-defined wavelength, and thus momentum. And conversely, when momentum, and thus wavelength, is relatively well defined, the wave looks long and sinusoidal, and therefore it has a very ill-defined position.

De Broglie himself had proposed a pilot wave construct to explain the observed waveâparticle duality. In this view, each particle has a well-defined position and momentum, but is guided by a wave function derived from SchrĂ¶dinger's equation. The pilot wave theory was initially rejected because it generated non-local effects when applied to systems involving more than one particle. Non-locality, however, soon became established as an integral feature of quantum theory and David Bohm extended de Broglie's model to explicitly include it.

In the resulting representation, also called the
de BroglieâBohm theory or Bohmian mechanics,^{
[22]} the waveâparticle duality vanishes, and explains the wave behaviour as a scattering with wave appearance, because the particle's motion is subject to a guiding equation or
quantum potential.

This idea seems to me so natural and simple, to resolve the waveâparticle dilemma in such a clear and ordinary way, that it is a great mystery to me that it was so generally ignored.

^{ [23]}â J.S.Bell

The best illustration of the *pilot-wave model* was given by Couder's 2010 "walking droplets" experiments,^{
[24]} demonstrating the pilot-wave behaviour in a macroscopic mechanical analog.^{
[21]}

Since the demonstrations of wave-like properties in
photons and
electrons, similar experiments have been conducted with
neutrons and
protons. Among the most famous experiments are those of
Estermann and
Otto Stern in 1929.^{
[25]}
Authors of similar recent experiments with atoms and molecules, described below, claim that these larger particles also act like waves.

A dramatic series of experiments emphasizing the action of
gravity in relation to waveâparticle duality was conducted in the 1970s using the
neutron interferometer.^{
[26]} Neutrons, one of the components of the
atomic nucleus, provide much of the mass of a nucleus and thus of ordinary matter. In the neutron interferometer, they act as quantum-mechanical waves directly subject to the force of gravity. While the results were not surprising since gravity was known to act on everything, including light (see
tests of general relativity and the
PoundâRebka falling photon experiment), the self-interference of the quantum mechanical wave of a massive
fermion in a gravitational field had never been experimentally confirmed before.

In 1999, the diffraction of C_{60}
fullerenes by researchers from the
University of Vienna was reported.^{
[27]} Fullerenes are comparatively large and massive objects, having an atomic mass of about 720
u. The
de Broglie wavelength of the incident beam was about 2.5
pm, whereas the diameter of the molecule is about 1
nm, about 400 times larger. In 2012, these far-field diffraction experiments could be extended to
phthalocyanine molecules and their heavier derivatives, which are composed of 58 and 114 atoms respectively. In these experiments the build-up of such interference patterns could be recorded in real time and with single molecule sensitivity.^{
[28]}

In 2003, the Vienna group also demonstrated the wave nature of
tetraphenylporphyrin^{
[29]}âa flat biodye with an extension of about 2 nm and a mass of 614 u. For this demonstration they employed a near-field
Talbot Lau interferometer.^{
[30]}^{
[31]} In the same interferometer they also found interference fringes for C_{60}F_{48}, a fluorinated
buckyball with a mass of about 1600 u, composed of 108 atoms.^{
[29]} Large molecules are already so complex that they give experimental access to some aspects of the quantum-classical interface, i.e., to certain
decoherence mechanisms.^{
[32]}^{
[33]} In 2011, the interference of molecules as heavy as 6910 u could be demonstrated in a KapitzaâDiracâTalbotâLau interferometer.^{
[34]} In 2013, the interference of molecules beyond 10,000 u has been demonstrated.^{
[35]}

Whether objects heavier than the
Planck mass (about the weight of a large bacterium) have a de Broglie wavelength is theoretically unclear and experimentally unreachable; above the Planck mass a particle's
Compton wavelength would be smaller than the
Planck length and its own
Schwarzschild radius, a scale at which current theories of physics may break down or need to be replaced by more general ones.^{
[36]}

Couder, Fort, *et al.* showed^{
[37]} that macroscopic oil droplets on a vibrating fluid bath can be used as an analogue model of waveâparticle duality; a localized droplet creates periodical wave field around itself. Resonant interaction between the droplet and its own wave field exhibits behaviour analogous to quantum particles: interference in double-slit experiment,^{
[38]} unpredictable tunneling^{
[39]} (depending in complicated way on practically hidden state of field), orbit quantization^{
[40]} (that particle has to 'find a resonance' with field perturbations it createsâafter one orbit, its internal phase has to return to the initial state) and
Zeeman effect.^{
[41]} Note that other single and double slit experiments ^{
[42]}^{
[43]} have shown that wall-droplet interactions rather than diffraction or interference of the pilot wave may be responsible for the observed hydrodynamic patterns, which are different from slit-induced interference patterns exhibited by quantum particles.

Waveâparticle duality is deeply embedded into the foundations of
quantum mechanics. In the
formalism of the theory, all the information about a particle is encoded in its
wave function, a complex-valued function roughly analogous to the amplitude of a wave at each point in space. This function evolves according to
SchrĂ¶dinger equation. For particles with mass this equation has solutions that follow the form of the wave equation. Propagation of such waves leads to wave-like phenomena such as interference and diffraction. Particles without mass, like photons, have no solutions of the SchrĂ¶dinger equation. Instead of a particle wave function that localizes mass in space, a photon wave function can be constructed from Einstein kinematics to localize energy in spatial coordinates.^{
[44]}

The particle-like behaviour is most evident due to phenomena associated with measurement in quantum mechanics. Upon measuring the location of the particle, the particle will be forced into a more localized state as given by the uncertainty principle. When viewed through this formalism, the measurement of the wave function will randomly lead to wave function collapse to a sharply peaked function at some location. For particles with mass, the likelihood of detecting the particle at any particular location is equal to the squared amplitude of the wave function there. The measurement will return a well-defined position, and is subject to Heisenberg's uncertainty principle.

Following the development of quantum field theory the ambiguity disappeared. The field permits solutions that follow the wave equation, which are referred to as the wave functions. The term particle is used to label the irreducible representations of the Lorentz group that are permitted by the field. An interaction as in a Feynman diagram is accepted as a calculationally convenient approximation where the outgoing legs are known to be simplifications of the propagation and the internal lines are for some order in an expansion of the field interaction. Since the field is non-local and quantized, the phenomena that previously were thought of as paradoxes are explained. Within the limits of the waveâparticle duality the quantum field theory gives the same results.

There are two ways to visualize the wave-particle behaviour: by the standard model and by the de BroglieâBohm theory.

Below is an illustration of waveâparticle duality as it relates to de Broglie's hypothesis and Heisenberg's Uncertainty principle, in terms of the position and momentum space wavefunctions for one spinless particle with mass in one dimension. These wavefunctions are Fourier transforms of each other.

The more localized the position-space wavefunction, the more likely the particle is to be found with the position coordinates in that region, and correspondingly the momentum-space wavefunction is less localized so the possible momentum components the particle could have are more widespread.

Conversely, the more localized the momentum-space wavefunction, the more likely the particle is to be found with those values of momentum components in that region, and correspondingly the less localized the position-space wavefunction, so the position coordinates the particle could occupy are more widespread.

Waveâparticle duality is an ongoing conundrum in modern physics. Most physicists accept waveâparticle duality as the best explanation for a broad range of observed phenomena; however, it is not without controversy. Alternative views are also presented here. These views are not generally accepted by mainstream physics, but serve as a basis for valuable discussion within the community.

The
pilot wave model, was originally developed by
Louis de Broglie and further developed by
David Bohm into the
hidden variable theory. The phrase âhidden variableâ is misleading since the variable in question is the positions of the particles.^{
[45]} Instead of duality, the pilot wave model proposes that both wave and particle are present with the wave guiding the particle in a
deterministic fashion. The wave in question is the wavefunction obeying SchrĂ¶dinger's equation. Bohm's formulation is intended to be classical, but it has to incorporate a distinctly non-classical
feature: a nonlocal force ("
quantum potential") acting on the particles.

Bohm's original purpose (1952) âwas to show that an alternative to the Copenhagen interpretation is at least logically possible.^{
[46]} Soon after he set the project aside and did
not revive it until he met
Basil Hiley in 1961 when both were at Birbeck College (University of London). Bohm and Hiley then wrote extensively on the theory and it gained a wider audience. This idea is held by a significant minority within the physics community.^{
[47]}

The
Afshar experiment^{
[48]} (2007) may suggest that it is possible to simultaneously observe both wave and particle properties of photons. This claim is, however, disputed by other scientists.^{
[49]}^{
[50]}^{
[51]}^{
[52]}

Carver Mead, an American scientist and professor at Caltech, said that the duality can be replaced by a "wave-only" view. In his book *Collective Electrodynamics: Quantum Foundations of Electromagnetism* (2000), Mead purports to analyze the behaviour of
electrons and
photons purely in terms of electron wave functions, and attributes the apparent particle-like behaviour to quantization effects and eigenstates. According to reviewer David Haddon:^{
[53]}

Mead has cut the Gordian knot of quantum complementarity. He claims that atoms, with their neutrons, protons, and electrons, are not particles at all but pure waves of matter. Mead cites as the gross evidence of the exclusively wave nature of both light and matter the discovery between 1933 and 1996 of ten examples of pure wave phenomena, including the ubiquitous laser of CD players, the self-propagating electrical currents of superconductors, and the BoseâEinstein condensate of atoms.

Albert Einstein, who, in his search for a
Unified Field Theory, did not accept waveâparticle duality, wrote:^{
[54]}

This double nature of radiation (and of material corpuscles) ... has been interpreted by quantum-mechanics in an ingenious and amazingly successful fashion. This interpretation ... appears to me as only a temporary way out...

The
many-worlds interpretation (MWI) is sometimes presented as a waves-only theory, including by its originator,
Hugh Everett who referred to MWI as "the wave interpretation".^{
[55]}

The *three wave hypothesis* of R. Horodecki relates the particle to wave.^{
[56]}^{
[57]} The hypothesis implies that a massive particle is an intrinsically spatially, as well as temporally extended, wave phenomenon by a nonlinear law.

The *deterministic collapse theory*^{
[58]} considers collapse and measurement as two independent physical processes. Collapse occurs when two wavepackets spatially overlap and satisfy a mathematical criterion, which depends on the parameters of both wavepackets. It is a contraction to the overlap volume. In a measurement apparatus one of the two wavepackets is one of the atomic clusters, which constitute the apparatus, and the wavepackets collapse to at most the volume of such a cluster. This mimics the action of a point particle.

Hegerfeldt's theorem, which appears to demonstrates the incompatibility of the existence of localized discrete particles with the combination of the principles of quantum mechanics and special relativity, has also been used to support the conclusion that reality must be described solely in terms of field-based formulations.^{
[59]}

Still in the days of the
old quantum theory, a pre-quantum-mechanical version of waveâparticle duality was pioneered by
William Duane,^{
[60]} and developed by others including
Alfred LandĂ©.^{
[61]} Duane explained diffraction of
x-rays by a crystal in terms solely of their particle aspect. The deflection of the trajectory of each diffracted photon was explained as due to
quantized momentum transfer from the spatially regular structure of the diffracting crystal.^{
[62]}

It has been argued that there are never exact particles or waves, but only some compromise or intermediate between them. For this reason, in 1928
Arthur Eddington^{
[63]} coined the name "*wavicle*" to describe the objects although it is not regularly used today. One consideration
is that zero-dimensional
mathematical points cannot be observed. Another is that the formal representation of such points, the
Dirac delta function is unphysical, because it cannot be
normalized. Parallel arguments apply to single-frequency wave states.
Roger Penrose states:^{
[64]}

Such 'position states' are idealized wavefunctions in the opposite sense from the momentum states. Whereas the momentum states are infinitely spread out, the position states are infinitely concentrated. Neither is normalizable [...].

Although it is difficult to draw a line separating waveâparticle duality from the rest of quantum mechanics, it is nevertheless possible to list some applications of this basic idea.

- Waveâparticle duality is exploited in electron microscopy, where the small wavelengths associated with the electron can be used to view objects much smaller than what is visible using visible light.
- Similarly, neutron diffraction uses neutrons with a wavelength of about 0.1 nm, the typical spacing of atoms in a solid, to determine the structure of solids.
- Photos are now able to show this dual nature, which may lead to new ways of examining and recording this behaviour.
^{ [65]}

- Afshar experiment
- Arago spot
- Basic concepts of quantum mechanics
- Complementarity (physics)
- Einstein's thought experiments
- EnglertâGreenbergerâYasin duality relation
- EPR paradox
- Faraday wave
- Hanbury Brown and Twiss effect
- KapitsaâDirac effect
- Photon polarization
- Scattering theory
- Wavelet
- Wheeler's delayed choice experiment

**^**Albert Einstein, Leopold Infeld (1938).*The Evolution of Physics: The Growth of Ideas from Early Concepts to Relativity and Quanta*. Cambridge University Press. Bibcode: 1938epgi.book.....E.`{{ cite book}}`

: CS1 maint: uses authors parameter ( link) Quoted in Harrison, David (2002). "Complementarity and the Copenhagen Interpretation of Quantum Mechanics".*UPSCALE*. Dept. of Physics, U. of Toronto. Retrieved 2008-06-21.**^**Walter Greiner (2001).*Quantum Mechanics: An Introduction*. Springer. ISBN 978-3-540-67458-0.**^**R. Eisberg & R. Resnick (1985).*Quantum Physics of Atoms, Molecules, Solids, Nuclei, and Particles*(2nd ed.). John Wiley & Sons. pp. 59â60. ISBN 978-0-471-87373-0.For both large and small wavelengths, both matter and radiation have both particle and wave aspects.... But the wave aspects of their motion become more difficult to observe as their wavelengths become shorter.... For ordinary macroscopic particles the mass is so large that the momentum is always sufficiently large to make the de Broglie wavelength small enough to be beyond the range of experimental detection, and classical mechanics reigns supreme.

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"A conjecture concerning determinism, reduction, and measurement in quantum mechanics".*Quantum Studies: Mathematics and Foundations*.**3**(4): 279â292. arXiv: 1204.0614. doi: 10.1007/s40509-016-0077-7. S2CID 32523066.**^**Halvorson, Hans; Clifton, Rob (November 2002). "No place for particles in relativistic quantum theories?".*Ontological Aspects of Quantum Field Theory*. pp. 181â213. arXiv: quant-ph/0103041. doi: 10.1142/9789812776440_0010. ISBN 978-981-238-182-8. S2CID 8845639.**^**Duane, W. (1923). "The Transfer in Quanta of Radiation Momentum to Matter".*Proceedings of the National Academy of Sciences of the United States of America*.**9**(5): 158â164. Bibcode: 1923PNAS....9..158D. doi: 10.1073/pnas.9.5.158. PMC 1085314. PMID 16576688.**^**LandĂ©, A. (1951).*Quantum Mechanics*, Sir Isaac Pitman and Sons, London, pp. 19â22.**^**Heisenberg, W. (1930).*The Physical Principles of the Quantum Theory*, translated by C. Eckart and F.C. Hoyt, University of Chicago Press, Chicago, pp. 77â78.**^**Eddington, Arthur Stanley (1928).*The Nature of the Physical World*. Cambridge, UK: MacMillan. pp. 201.**^**Penrose, Roger (2007).*The Road to Reality: A Complete Guide to the Laws of the Universe*. Vintage. p. 521, Â§21.10. ISBN 978-0-679-77631-4.**^**Papageorgiou, Nik (2 March 2015). "Press release: The first ever photograph of light as both a particle and wave". Ecole Polytechnique Federale de Lausanne.`{{ cite journal}}`

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