Hydrogen economy

From Wikipedia
https://en.wikipedia.org/wiki/Hydrogen_economy

The hydrogen economy is using hydrogen to decarbonize economic sectors which are hard to electrify. [1] In order to phase out fossil fuels and limit climate change, hydrogen can be created from water using renewable sources such as wind and solar, and its combustion only releases water vapor to the atmosphere. [2] [3]

Hydrogen is a powerful fuel, and a frequent component in rocket fuel, but numerous technical challenges prevent the creation of a large-scale hydrogen economy. These include the difficulty of developing long-term storage, pipelines and engine equipment; a relative lack of off-the-shelf engine technology that can currently run safely on hydrogen; safety concerns due to the high reactivity of hydrogen fuel with environmental oxygen in the air; the expense of producing it by electrolysis; and a lack of efficient photochemical water splitting technology. Hydrogen can also be the fuel in a fuel cell, which produces electricity with high efficiency in a process which is the reverse of the electrolysis of water. The hydrogen economy is nevertheless slowly developing as a small part of the low-carbon economy. [4] As of 2019, hydrogen is mainly used as an industrial feedstock, primarily for the production of ammonia and methanol, and in petroleum refining. Although initially hydrogen gas was thought not to occur naturally in convenient reservoirs, it is now demonstrated that this is not the case; a hydrogen system is currently being exploited in the region of Bourakebougou, Mali, producing electricity for the surrounding villages. [5] More discoveries of naturally occurring hydrogen in continental, on-shore geological environments have been made in recent years [6] and open the way to the novel field of natural or native hydrogen, supporting energy transition efforts. [7] [8] As of 2019, almost all (95%) of the world's 70 million tons of hydrogen consumed yearly in industrial processing, [9] significantly in fertilizer for 45 percent of world's food, [10] are produced by steam methane reforming (SMR) that also releases the greenhouse gas carbon dioxide. [11]

A possible less-polluting alternative is the newer technology methane pyrolysis, [12] [13] [14] though SMR with carbon capture and storage (CCS) may also much reduce carbon emissions. Small amounts of hydrogen (5%) are produced by the dedicated production of hydrogen from water, usually as a byproduct of the process of generating chlorine from seawater. As of 2018 there is not enough cheap clean electricity (renewable and nuclear) for this hydrogen to become a significant part of the low-carbon economy, and carbon dioxide is a by-product of the SMR process, [15] but it can be captured and stored.

Rationale

Elements of the hydrogen economy

In the current hydrocarbon economy, heating is fueled primarily by natural gas and transportation by petroleum. Burning of hydrocarbon fuels emits carbon dioxide and other pollutants. The demand for energy is increasing, particularly in China, India, and other developing countries. Hydrogen can be an environmentally cleaner source of energy to end-users, without release of pollutants such as particulates or carbon dioxide. [16]

Hydrogen has a high energy density by weight but has a low energy density by volume. Even when highly compressed, stored in solids, or liquified, the energy density by volume is only 1/4 that of gasoline, although the energy density by weight is approximately three times that of gasoline or natural gas. Hydrogen can help to decarbonize long-haul transport, chemicals, and iron and steel [17] and has the potential to transport renewable energy long distance and store it long term, for example from wind power or solar electricity. [18]

History

The term hydrogen economy was coined by John Bockris during a talk he gave in 1970 at General Motors (GM) Technical Center. [19] The concept was proposed earlier by geneticist J.B.S. Haldane. [20]

A hydrogen economy was proposed by the University of Michigan to solve some of the negative effects of using hydrocarbon fuels where the carbon is released to the atmosphere (as carbon dioxide, carbon monoxide, unburnt hydrocarbons, etc.). Modern interest in the hydrogen economy can generally be traced to a 1970 technical report by Lawrence W. Jones of the University of Michigan. [21]

A spike in attention for the concept during the 2000s was repeatedly described as hype by some critics and proponents of alternative technologies. [22] [23] [24] Interest in the energy carrier resurged in the 2010s, notably by the forming of the Hydrogen Council in 2017. Several manufacturers released hydrogen fuel cell cars commercially, with manufacturers such as Toyota and industry groups in China planning to increase numbers of the cars into the hundreds of thousands over the next decade. [25] [26]

Current hydrogen market

Timeline

Hydrogen production is a large and growing industry: with as of 2019 about 70 million tonnes of dedicated production per year, larger than the primary energy supply of Germany. [27]

As of 2019 fertiliser production and oil refining are the main uses. [28] About half[ citation needed] is used in the Haber process to produce ammonia (NH3), which is then used directly or indirectly as fertilizer. [29] Because both the world population and the intensive agriculture used to support it are growing, ammonia demand is growing. Ammonia can be used as a safer and easier indirect method of transporting hydrogen. Transported ammonia can be then converted back to hydrogen at the bowser by a membrane technology. [30]

The other half[ citation needed] of current hydrogen production is used to convert heavy petroleum sources into lighter fractions suitable for use as fuels. This latter process is known as hydrocracking. Hydrocracking represents an even larger growth area, since rising oil prices encourage oil companies to extract poorer source material, such as oil sands and oil shale. The scale economies inherent in large-scale oil refining and fertilizer manufacture make possible on-site production and "captive" use. Smaller quantities of "merchant" hydrogen are manufactured and delivered to end users as well.

As of 2019 almost all hydrogen production is from fossil fuels, and emits 830 million tonnes of carbon dioxide per year. [27] The distribution of production reflects the effects of thermodynamic constraints on economic choices: of the four methods for obtaining hydrogen, partial combustion of natural gas in a NGCC (natural gas combined cycle) power plant offers the most efficient chemical pathway and the greatest off-take of usable heat energy.[ citation needed]

The large market and sharply rising prices in fossil fuels have also stimulated great interest in alternate, cheaper means of hydrogen production. [31] [32]

Production, storage, infrastructure

As of 2002, hydrogen is mainly produced (>90%) from fossil sources. [33][ better source needed]

Color codes

Hydrogen is often referred to by various colors to indicate its origin. As shown below, some production sources have more than one label with the more common listed first. Although the usage of color codes is not standardized, neither is it ambiguous.[ citation needed]

Colors that refer to method of production
Color Production source Notes References
green renewable energy and electricity via electrolysis of water [34]: 28 
turquoise Hydrogen unstable storage; thermal splitting of methane via methane pyrolysis [34]: 28  [35]: 2 
blue Hydrogen storage, see surface chemistry; hydrocarbons with carbon capture and storage CCS networks required [34]: 28 
gray hydrogen metals [34]: 28  [36]: 10  [35]: 2 
brown or black hydrogen minimum, coal [37]: 91 
purple or pink or red Hydrogen storages; nuclear power without electrolysis of water [35]: 2 
yellow low level hydrogen in solar powers via photovoltaic https://www.nationalgrid.com/stories/energy-explained/hydrogen-colour-spectrum
white medical hydrogen refers to naturally occurring hydrogen [38]

Methods of production

Molecular hydrogen was discovered in the Kola Superdeep Borehole. It is unclear how much molecular hydrogen is available in natural reservoirs, but at least one company [39] specializes in drilling wells to extract hydrogen. Most hydrogen in the lithosphere is bonded to oxygen in water. Manufacturing elemental hydrogen requires the consumption of a hydrogen carrier such as a fossil fuel or water. The former carrier consumes the fossil resource and in the steam methane reforming (SMR) process produces greenhouse gas carbon dioxide. However in the newer methane pyrolysis process no greenhouse gas carbon dioxide is produced. These processes typically require no further energy input beyond the fossil fuel.

Illustrating inputs and outputs of steam reforming of natural gas, a process to produce hydrogen. As of 2020, the carbon sequestrastion step is not in commercial use.

Decomposing water, the latter carrier, requires electrical or heat input, generated from some primary energy source (fossil fuel, nuclear power or a renewable energy). Hydrogen produced by zero emission energy sources such as electrolysis of water using wind power, solar power, nuclear power, hydro power, wave power or tidal power is referred to as green hydrogen. [40] When derived from natural gas by zero greenhouse emission methane pyrolysis, it is referred to as turquoise hydrogen. [41] When fossil fuel derived with greenhouse gas emissions, is generally referred to as grey hydrogen. if most of the carbon dioxide emission is captured, it is referred to as blue hydrogen. [42] Hydrogen produced from coal may be referred to as brown hydrogen. [43]

Current production methods

Steam reforming – gray or blue

Hydrogen is industrially produced from steam reforming (SMR), which uses natural gas. [44] The energy content of the produced hydrogen is less than the energy content of the original fuel, some of it being lost as excess heat during production. Steam reforming emits carbon dioxide, a greenhouse gas.

Methane pyrolysis – turquoise

Illustrating inputs and outputs of methane pyrolysis, a process to produce Hydrogen

Pyrolysis of methane (natural gas) with a one-step process [45] bubbling methane through a molten metal catalyst is a "no greenhouse gas" approach to produce hydrogen that was perfected in 2017 and now being tested at scale. [14] [41] The process is conducted at high temperatures (1065 °C). [13] [46] [47] [48] Producing 1 kg of hydrogen requires about 5 kWh of electricity for process heat.

CH
4
(g) → C(s) + 2 H
2
(g) ΔH° = 74 kJ/mol

The industrial quality solid carbon may be sold as manufacturing feedstock or landfilled (no pollution).

Electrolysis of water – green or purple

Hydrogen production via Electrolysis graphic
Illustrating inputs and outputs of simple electrolysis of water production of hydrogen

Hydrogen can be made via high pressure electrolysis, low pressure electrolysis of water, or a range of other emerging electrochemical processes such as high temperature electrolysis or carbon assisted electrolysis. [49] However, current best processes for water electrolysis have an effective electrical efficiency of 70-80%, [50] [51] [52] so that producing 1 kg of hydrogen (which has a specific energy of 143 MJ/kg or about 40 kWh/kg) requires 50–55 kWh of electricity.

In parts of the world, steam methane reforming is between $1–3/kg on average excluding hydrogen gas pressurization cost. This makes production of hydrogen via electrolysis cost competitive in many regions already, as outlined by Nel Hydrogen [53] and others, including an article by the IEA [54] examining the conditions which could lead to a competitive advantage for electrolysis.

A small part (2% in 2019 [55]) is produced by electrolysis using electricity and water, consuming approximately 50 to 55 kilowatt-hours of electricity per kilogram of hydrogen produced. [56]

Kværner process

The Kværner process or Kvaerner carbon black and hydrogen process (CB&H) [33] is a method, developed in the 1980s by a Norwegian company of the same name, for the production of hydrogen from hydrocarbons (CnHm), such as methane, natural gas and biogas. Of the available energy of the feed, approximately 48% is contained in the hydrogen, 40% is contained in activated carbon and 10% in superheated steam. [57]

Experimental production methods

Biological production

Fermentative hydrogen production is the fermentative conversion of organic substrate to biohydrogen manifested by a diverse group of bacteria using multi enzyme systems involving three steps similar to anaerobic conversion. Dark fermentation reactions do not require light energy, so they are capable of constantly producing hydrogen from organic compounds throughout the day and night. Photofermentation differs from dark fermentation because it only proceeds in the presence of light. For example, photo-fermentation with Rhodobacter sphaeroides SH2C can be employed to convert small molecular fatty acids into hydrogen. [58] Electrohydrogenesis is used in microbial fuel cells where hydrogen is produced from organic matter (e.g. from sewage, or solid matter [59]) while 0.2 - 0.8 V is applied.

Biological hydrogen can be produced in an algae bioreactor. In the late 1990s it was discovered that if the algae is deprived of sulfur it will switch from the production of oxygen, i.e. normal photosynthesis, to the production of hydrogen. [60]

Biological hydrogen can be produced in bioreactors that use feedstocks other than algae, the most common feedstock being waste streams. The process involves bacteria feeding on hydrocarbons and excreting hydrogen and CO2. The CO2 can be sequestered successfully by several methods, leaving hydrogen gas. In 2006-2007, NanoLogix first demonstrated a prototype hydrogen bioreactor using waste as a feedstock at Welch's grape juice factory in North East, Pennsylvania (U.S.). [61]

Biocatalysed electrolysis

Besides regular electrolysis, electrolysis using microbes is another possibility. With biocatalysed electrolysis, hydrogen is generated after running through the microbial fuel cell and a variety of aquatic plants can be used. These include reed sweetgrass, cordgrass, rice, tomatoes, lupines, and algae [62]

High-pressure electrolysis

High pressure electrolysis is the electrolysis of water by decomposition of water (H2O) into oxygen (O2) and hydrogen gas (H2) by means of an electric current being passed through the water. The difference with a standard electrolyzer is the compressed hydrogen output around 120-200 bar (1740-2900 psi, 12–20 MPa). [63] By pressurising the hydrogen in the electrolyser, through a process known as chemical compression, the need for an external hydrogen compressor is eliminated, [64] the average energy consumption for internal compression is around 3%. [65] European largest (1 400 000 kg/a, High-pressure Electrolysis of water, alkaline technology) hydrogen production plant is operating at Kokkola, Finland. [66]

High-temperature electrolysis

Hydrogen can be generated from energy supplied in the form of heat and electricity through high-temperature electrolysis (HTE). Because some of the energy in HTE is supplied in the form of heat, less of the energy must be converted twice (from heat to electricity, and then to chemical form), and so potentially far less energy is required per kilogram of hydrogen produced.

While nuclear-generated electricity could be used for electrolysis, nuclear heat can be directly applied to split hydrogen from water. High temperature (950–1000 °C) gas cooled nuclear reactors have the potential to split hydrogen from water by thermochemical means using nuclear heat. Research into high-temperature nuclear reactors may eventually lead to a hydrogen supply that is cost-competitive with natural gas steam reforming. General Atomics predicts that hydrogen produced in a High Temperature Gas Cooled Reactor (HTGR) would cost $1.53/kg. In 2003, steam reforming of natural gas yielded hydrogen at $1.40/kg. In 2005 natural gas prices, hydrogen costs $2.70/kg.

High-temperature electrolysis has been demonstrated in a laboratory, at 108  MJ (thermal) per kilogram of hydrogen produced, [67] but not at a commercial scale. In addition, this is lower-quality "commercial" grade Hydrogen, unsuitable for use in fuel cells. [68]

Photoelectrochemical water splitting

Using electricity produced by photovoltaic systems offers the cleanest way to produce hydrogen. Water is broken into hydrogen and oxygen by electrolysis – a photoelectrochemical cell (PEC) process which is also named artificial photosynthesis. [69] William Ayers at Energy Conversion Devices demonstrated and patented the first multijunction high efficiency photoelectrochemical system for direct splitting of water in 1983. [70] This group demonstrated direct water splitting now referred to as an "artificial leaf" or "wireless solar water splitting" with a low cost thin film amorphous silicon multijunction sheet immersed directly in water. Hydrogen evolved on the front amorphous silicon surface decorated with various catalysts while oxygen evolved off the back metal substrate. A Nafion membrane above the multijunction cell provided a path for ion transport. Their patent also lists a variety of other semiconductor multijunction materials for the direct water splitting in addition to amorphous silicon and silicon germanium alloys. Research continues towards developing high-efficiency multi-junction cell technology at universities and the photovoltaic industry. If this process is assisted by photocatalysts suspended directly in water instead of using photovoltaic and an electrolytic system, the reaction is in just one step, which can improve efficiency. [71] [72]

Photoelectrocatalytic production

A method studied by Thomas Nann and his team at the University of East Anglia consists of a gold electrode covered in layers of indium phosphide (InP) nanoparticles. They introduced an iron-sulfur complex into the layered arrangement, which when submerged in water and irradiated with light under a small electric current, produced hydrogen with an efficiency of 60%. [73]

In 2015, it was reported that Panasonic Corp. has developed a photocatalyst based on niobium nitride that can absorb 57% of sunlight to support the decomposition of water to produce hydrogen gas. [74] The company plans to achieve commercial application "as early as possible", not before 2020.

Concentrating solar thermal

Very high temperatures are required to dissociate water into hydrogen and oxygen. A catalyst is required to make the process operate at feasible temperatures. Heating the water can be achieved through the use of water concentrating solar power. Hydrosol-2 is a 100-kilowatt pilot plant at the Plataforma Solar de Almería in Spain which uses sunlight to obtain the required 800 to 1,200 °C to heat water. Hydrosol II has been in operation since 2008. The design of this 100-kilowatt pilot plant is based on a modular concept. As a result, it may be possible that this technology could be readily scaled up to the megawatt range by multiplying the available reactor units and by connecting the plant to heliostat fields (fields of sun-tracking mirrors) of a suitable size. [75]

Thermochemical production

There are more than 352 [76] thermochemical cycles which can be used for water splitting, [77] around a dozen of these cycles such as the iron oxide cycle, cerium(IV) oxide-cerium(III) oxide cycle, zinc zinc-oxide cycle, sulfur-iodine cycle, copper-chlorine cycle and hybrid sulfur cycle, aluminum aluminum-oxide cycle, are under research and in testing phase to produce hydrogen and oxygen from water and heat without using electricity. [78] These processes can be more efficient than high-temperature electrolysis, typical in the range from 35% - 49% LHV efficiency. Thermochemical production of hydrogen using chemical energy from coal or natural gas is generally not considered, because the direct chemical path is more efficient.

None of the thermochemical hydrogen production processes have been demonstrated at production levels, although several have been demonstrated in laboratories.

Microwaving plastics

A 97% recovery of hydrogen has been achieved through microwaving plastics for a few seconds that have been ground and mixed with iron oxide and aluminium oxide. [79]

Hydrogen as a byproduct of other chemical processes

The industrial production of chlorine and caustic soda by electrolysis generates a sizable amount of Hydrogen as a byproduct. In the port of Antwerp a 1MW demonstration fuel cell power plant is powered by such byproduct. This unit has been operational since late 2011. [80] The excess hydrogen is often managed with a hydrogen pinch analysis.

Gas generated from coke ovens in steel production is similar to Syngas with 60% hydrogen by volume. [81] The hydrogen can be extracted from the coke oven gas economically. [82]

Storage

Although molecular hydrogen has very high energy density on a mass basis, partly because of its low molecular weight, as a gas at ambient conditions it has very low energy density by volume. If it is to be used as fuel stored on board the vehicle, pure hydrogen gas must be stored in an energy-dense form to provide sufficient driving range.

Pressurized hydrogen gas

Increasing gas pressure improves the energy density by volume making for smaller container tanks. The standard material for holding pressurised hydrogen in tube trailers is steel (there is no hydrogen embrittlement problem with hydrogen gas). Tanks made of carbon and glass fibres reinforcing plastic as fitted in Toyota Marai and Kenworth trucks are required to meet safety standards. Few materials are suitable for tanks as hydrogen being a small molecule tends to diffuse through many polymeric materials. The most common on board hydrogen storage in today's 2020 vehicles is hydrogen at pressure 700bar = 70MPa. The energy cost of compressing hydrogen to this pressure is significant.

Pressurized gas pipelines are always made of steel and operate at much lower pressures than tube trailers.

Liquid hydrogen

Alternatively, higher volumetric energy density liquid hydrogen or slush hydrogen may be used. However, liquid hydrogen is cryogenic and boils at 20.268 K (–252.882 °C or –423.188 °F). Cryogenic storage cuts weight but requires large liquification energies. The liquefaction process, involving pressurizing and cooling steps, is energy intensive. [83] The liquefied hydrogen has lower energy density by volume than gasoline by approximately a factor of four, because of the low density of liquid hydrogen – there is actually more hydrogen in a litre of gasoline (116 grams) than there is in a litre of pure liquid hydrogen (71 grams). Liquid hydrogen storage tanks must also be well insulated to minimize boil off.

Japan has a liquid hydrogen (LH2) storage facility at a terminal in Kobe, and are expected to receive the first shipment of liquid hydrogen via LH2 carrier in 2020. [84] Hydrogen is liquified by reducing its temperature to -253 °C, similar to liquified natural gas (LNG) which is stored at -162 °C. A potential efficiency loss of 12.79% can be achieved, or 4.26kWh/kg out of 33.3kWh/kg. [85]

Liquid organic hydrogen carriers (LOHC)

Storage as hydride

Distinct from storing molecular hydrogen, hydrogen can be stored as a chemical hydride or in some other hydrogen-containing compound. Hydrogen gas is reacted with some other materials to produce the hydrogen storage material, which can be transported relatively easily. At the point of use the hydrogen storage material can be made to decompose, yielding hydrogen gas. As well as the mass and volume density problems associated with molecular hydrogen storage, current barriers to practical storage schemes stem from the high pressure and temperature conditions needed for hydride formation and hydrogen release. For many potential systems hydriding and dehydriding kinetics and heat management are also issues that need to be overcome. A French company McPhy Energy is developing the first industrial product, based on Magnesium Hydrate, already sold to some major clients such as Iwatani and ENEL.[ citation needed] Emergent hydride hydrogen storage technologies have achieved a compressed volume of less than 1/500.

Adsorption

A third approach is to adsorb molecular hydrogen on the surface of a solid storage material. Unlike in the hydrides mentioned above, the hydrogen does not dissociate/recombine upon charging/discharging the storage system, and hence does not suffer from the kinetic limitations of many hydride storage systems. Hydrogen densities similar to liquefied hydrogen can be achieved with appropriate adsorbent materials. Some suggested adsorbents include activated carbon, nanostructured carbons (including CNTs), MOFs, and hydrogen clathrate hydrate.

Underground hydrogen storage

'Available storage technologies, their capacity and discharge time.' COMMISSION STAFF WORKING DOCUMENT Energy storage – the role of electricity

Underground hydrogen storage is the practice of hydrogen storage in caverns, salt domes and depleted oil and gas fields. Large quantities of gaseous hydrogen have been stored in caverns by ICI for many years without any difficulties. [86] The storage of large quantities of liquid hydrogen underground can function as grid energy storage. The round-trip efficiency is approximately 40% (vs. 75-80% for pumped-hydro (PHES)), and the cost is slightly higher than pumped hydro. [87] Another study referenced by a European staff working paper found that for large scale storage, the cheapest option is hydrogen at €140/MWh for 2,000 hours of storage using an electrolyser, salt cavern storage and combined-cycle power plant. [88] The European project Hyunder [89] indicated in 2013 that for the storage of wind and solar energy an additional 85 caverns are required as it cannot be covered by PHES and CAES systems. [90] A German case study on storage of hydrogen in salt caverns found that if the German power surplus (7% of total variable renewable generation by 2025 and 20% by 2050) would be converted to hydrogen and stored underground, these quantities would require some 15 caverns of 500,000 cubic metres each by 2025 and some 60 caverns by 2050 – corresponding to approximately one third of the number of gas caverns currently operated in Germany. [91] In the US, Sandia Labs are conducting research into the storage of hydrogen in depleted oil and gas fields, which could easily absorb large amounts of renewably produced hydrogen as there are some 2.7 million depleted wells in existence. [92]

Power to gas

Power to gas is a technology which converts electrical power to a gas fuel. There are 2 methods, the first is to use the electricity for water splitting and inject the resulting hydrogen into the natural gas grid. The second (less efficient) method is used to convert carbon dioxide and water to methane, (see natural gas) using electrolysis and the Sabatier reaction. The excess power or off peak power generated by wind generators or solar arrays is then used for load balancing in the energy grid. Using the existing natural gas system for hydrogen Fuel cell maker Hydrogenics and natural gas distributor Enbridge have teamed up to develop such a power to gas system in Canada. [93]

Pipeline storage

A natural gas network may be used for the storage of hydrogen. Before switching to natural gas, the UK and German gas networks were operated using towngas, which for the most part consisted of hydrogen. The storage capacity of the German natural gas network is more than 200,000 GWh which is enough for several months of energy requirement. By comparison, the capacity of all German pumped storage power plants amounts to only about 40 GW·h. Similarly UK pumped storage is far less than the gas network. The transport of energy through a gas network is done with much less loss (<0.1%) than in a power network (8%). The use of the existing natural gas pipelines for hydrogen was studied by NaturalHy. [94] Ad van Wijk, a professor at Future Energy Systems TU Delft, also discusses the possibility of producing electricity in areas or countries with much sunlight (Sahara, Chile, Mexico, Namibia, Australia, New Zealand, ...) and transporting it (via ship, pipeline, ...) to the Netherlands. This being economically seen, still cheaper than producing it locally in the Netherlands. He also mentions that the energy transport capacity of gas lines are far higher than that of electricity lines coming into private houses (in the Netherlands) -30 kW vs 3 kW-. [95] [96]

Infrastructure

Praxair Hydrogen Plant

The hydrogen infrastructure would consist mainly of industrial hydrogen pipeline transport and hydrogen-equipped filling stations like those found on a hydrogen highway. Hydrogen stations which were not situated near a hydrogen pipeline would get supply via hydrogen tanks, compressed hydrogen tube trailers, liquid hydrogen trailers, liquid hydrogen tank trucks or dedicated onsite production.

Over 700 miles of hydrogen pipeline currently exist in the United States. Although expensive, pipelines are the cheapest way to move hydrogen over long distances. Hydrogen gas piping is routine in large oil-refineries, because hydrogen is used to hydrocrack fuels from crude oil.

Hydrogen piping can in theory be avoided in distributed systems of hydrogen production, where hydrogen is routinely made on site using medium or small-sized generators which would produce enough hydrogen for personal use or perhaps a neighborhood. In the end, a combination of options for hydrogen gas distribution may succeed.[ citation needed]

Hydrogen embrittlement is not a problem for hydrogen gas pipelines. Hydrogen embrittlement only happens with 'diffusible' hydrogen, i.e. atoms or ions. Hydrogen gas, however, is molecular (H2), and there is a very significant energy barrier to splitting it into atoms. [97]

The IEA recommends existing industrial ports be used for production and existing natural gas pipelines for transport: also international co-operation and shipping. [98]

South Korea and Japan, [99] which as of 2019 lack international electrical interconnectors, are investing in the hydrogen economy. [100] In March 2020, a production facility was opened in Namie, Fukushima Prefecture, claimed to be the world's largest. [101]

A key tradeoff: centralized vs. distributed production

In a future full hydrogen economy, primary energy sources and feedstock would be used to produce hydrogen gas as stored energy for use in various sectors of the economy. Producing hydrogen from primary energy sources other than coal and oil would result in lower production of the greenhouse gases characteristic of the combustion of coal and oil fossil energy resources. The importance of non-polluting methane pyrolysis of natural gas is becoming a recognized method for using current natural gas infrastructure investment to produce hydrogen and no greenhouse gas.

One key feature of a hydrogen economy would be that in mobile applications (primarily vehicular transport) energy generation and use could be decoupled. The primary energy source would need no longer travel with the vehicle, as it currently does with hydrocarbon fuels. Instead of tailpipes creating dispersed emissions, the energy (and pollution) could be generated from point sources such as large-scale, centralized facilities with improved efficiency. This would allow the possibility of technologies such as carbon sequestration, which are otherwise impossible for mobile applications. Alternatively, distributed energy generation schemes (such as small scale renewable energy sources) could be used, possibly associated with hydrogen stations.

Aside from the energy generation, hydrogen production could be centralized, distributed or a mixture of both. While generating hydrogen at centralized primary energy plants promises higher hydrogen production efficiency, difficulties in high-volume, long range hydrogen transportation (due to factors such as hydrogen damage and the ease of hydrogen diffusion through solid materials) makes electrical energy distribution attractive within a hydrogen economy. In such a scenario, small regional plants or even local filling stations could generate hydrogen using energy provided through the electrical distribution grid or methane pyrolysis of natural gas. While hydrogen generation efficiency is likely to be lower than for centralized hydrogen generation, losses in hydrogen transport could make such a scheme more efficient in terms of the primary energy used per kilogram of hydrogen delivered to the end user.

The proper balance between hydrogen distribution, long-distance electrical distribution and destination converted pyrolysis of natural gas is one of the primary questions that arises about the hydrogen economy.

Again the dilemmas of production sources and transportation of hydrogen can now be overcome using on site (home, business, or fuel station) generation of hydrogen from off grid renewable sources. [1].

Distributed electrolysis

Distributed electrolysis would bypass the problems of distributing hydrogen by distributing electricity instead. It would use existing electrical networks to transport electricity to small, on-site electrolysers located at filling stations. However, accounting for the energy used to produce the electricity and transmission losses would reduce the overall efficiency.

Uses

Industry

Steelmaking and ammonia production are industries which may become big users. [102]

For heating and cooking instead of natural gas

Hydrogen can replace some or all of the natural gas in gas grids. [103] As of 2020 the maximum in a grid is 20%. [104]

Fuel cells as alternative to internal combustion and electric batteries

One of the main offerings of a hydrogen economy is that the fuel can replace the fossil fuel burned in internal combustion engines and turbines as the primary way to convert chemical energy into kinetic or electrical energy, thereby eliminating greenhouse gas emissions and pollution from that engine. Ad van Wijk, a professor at Future Energy Systems TU Delft also mentions that hydrogen is better for larger vehicles - such as trucks, buses and ships - than electric batteries. [105] This because a 1 kg battery, as of 2019, can store 0.1 kWh a of energy whereas 1 kg of hydrogen has a usable capacity of 33 kWh. [106]

Although hydrogen can be used in conventional internal combustion engines, fuel cells, being electrochemical, have a theoretical efficiency advantage over heat engines. Fuel cells are more expensive to produce than common internal combustion engines.

Hydrogen gas must be distinguished as "technical-grade" (five nines pure, 99.999%) produced by methane pyrolysis or electrolysis, which is suitable for applications such as fuel cells, and "commercial-grade", which has carbon- and sulfur-containing impurities, but which can be produced by the slightly cheaper steam-reformation process that releases carbon dioxide greenhouse gas. Fuel cells require high-purity hydrogen because the impurities would quickly degrade the life of the fuel cell stack.

Much of the interest in the hydrogen economy concept is focused on the use of fuel cells to power hydrogen vehicles, particularly large trucks. Hydrogen fuel cells suffer from a low power-to-weight ratio. [107] Fuel cells are more efficient than internal combustion engines. If a practical method of hydrogen storage is introduced, and fuel cells become cheaper, they can be economically viable to power hybrid fuel cell/ battery vehicles, or purely fuel cell-driven ones. The combination of the fuel cell and electric motor is 2-3 times more efficient than an internal-combustion engine. [108] Capital costs of fuel cells have reduced significantly over recent years, with a modeled cost of $50/kW cited by the Department of Energy. [109]

Other fuel cell technologies based on the exchange of metal ions (e.g. zinc–air fuel cells) are typically more efficient at energy conversion than hydrogen fuel cells, but the widespread use of any electrical energy → chemical energy → electrical energy systems would necessitate the production of electricity.

In the short term hydrogen has been proposed as a method of reducing harmful diesel exhaust. [110]

Safety

Hydrogen has one of the widest explosive/ignition mix range with air of all the gases with few exceptions such as acetylene, silane, and ethylene oxide. This means that whatever the mix proportion between air and hydrogen, when ignited in an enclosed space a hydrogen leak will most likely lead to an explosion, not a mere flame. This makes the use of hydrogen particularly dangerous in enclosed areas such as tunnels or underground parking. [111] Pure hydrogen-oxygen flames burn in the ultraviolet color range and are nearly invisible to the naked eye, so a flame detector is needed to detect if a hydrogen leak is burning. Like natural gas, hydrogen is odorless and leaks cannot be detected by smell. This is the reason odorant chemical is injected into the natural gas to deliver the rotten-egg odor.

Hydrogen codes and standards are codes and standards for hydrogen fuel cell vehicles, stationary fuel cell applications and portable fuel cell applications. There are codes and standards for the safe handling and storage of hydrogen, for example the standard for the installation of stationary fuel cell power systems from the National Fire Protection Association.

Codes and standards have repeatedly been identified as a major institutional barrier to deploying hydrogen technologies and developing a hydrogen economy. As of 2019 international standards are needed for the transport, storage and traceability of environmental impact. [17]

One of the measures on the roadmap is to implement higher safety standards like early leak detection with hydrogen sensors. [112][ needs update] The Canadian Hydrogen Safety Program concluded that hydrogen fueling is as safe as, or safer than, compressed natural gas (CNG) fueling. [113] The European Commission has funded the first higher educational program in the world in hydrogen safety engineering at the University of Ulster. It is expected that the general public will be able to use hydrogen technologies in everyday life with at least the same level of safety and comfort as with today's fossil fuels.

Costs

H2 production cost ($-gge untaxed)[ globalize] at varying natural gas prices

Although much of an existing natural gas grid could be reused with 100% hydrogen, eliminating natural gas from a large area such as Britain would require huge investment. [114] Switching from natural gas to low-carbon heating is more costly if the carbon costs of natural gas are not reflected in its price. [115]

Power plant capacity that now goes unused at night could be used to produce green hydrogen, but this would not be enough; [116] therefore turquoise hydrogen from non-polluting methane pyrolysis or blue hydrogen with carbon capture and storage is needed, possibly after autothermal reforming of methane rather than steam methane reforming. [114]

As of 2020 green hydrogen costs between $2.50-6.80 per kilogram and turquoise hydrogen $1.40-2.40/kg or blue hydrogen $1.40-2.40/kg compared with high-carbon grey hydrogen at $1–1.80/kg. [116] Deployment of hydrogen can provide a cost-effective option to displace carbon polluting fossil fuels in applications where emissions reductions would otherwise be impractical and/or expensive. [117] These may include heat for buildings and industry, conversion of natural gas-fired power stations, [118] and fuel for aviation and importantly heavy trucks. [119]

In Australia, the Australian Renewable Energy Agency (ARENA) has invested $55 million in 28 hydrogen projects, from early stage research and development to early stage trials and deployments. The agency's stated goal is to produce hydrogen by electrolysis for $2 per kilogram, announced by Minister for Energy and Emissions Angus Taylor in a 2021 Low Emissions Technology Statement. [120]

In August 2021, Chris Jackson quit as chair of the UK Hydrogen and Fuel Cell Association, a leading hydrogen industry association, claiming that UK and Norwegian oil companies had intentionally inflated their cost projections for blue hydrogen in order to maximize future technology support payments by the UK government. [121]

Examples and pilot programs

A Mercedes-Benz O530 Citaro powered by hydrogen fuel cells, in Brno, Czech Republic.

The distribution of hydrogen for the purpose of transportation is currently[ when?] being tested around the world, particularly in the US ( California, Massachusetts), Canada, Japan, the EU ( Portugal, Norway, Denmark, Germany), and Iceland, but the cost is very high.

Several domestic U.S. automobile have developed vehicles using hydrogen, such as GM and Toyota. [122] However as of February 2020, infrastructure for hydrogen was underdeveloped except in some parts of California. [123] The United States have their own hydrogen policy.[ citation needed] A joint venture between NREL and Xcel Energy is combining wind power and hydrogen power in the same way in Colorado. [124] Hydro in Newfoundland and Labrador are converting the current wind-diesel Power System on the remote island of Ramea into a Wind-Hydrogen Hybrid Power Systems facility. [125] A similar pilot project on Stuart Island uses solar power, instead of wind power, to generate electricity. When excess electricity is available after the batteries are fully charged, hydrogen is generated by electrolysis and stored for later production of electricity by fuel cell. [126] The US also have a large natural gas pipeline system already in place. [127]

Countries in the EU which have a relatively large natural gas pipeline system already in place include Belgium, Germany, France, and the Netherlands. [127] In 2020, The EU launched its European Clean Hydrogen Alliance (ECHA). [128] [129]

The UK started a fuel cell pilot program in January 2004, the program ran two Fuel cell buses on route 25 in London until December 2005, and switched to route RV1 until January 2007. [130] The Hydrogen Expedition is currently working to create a hydrogen fuel cell-powered ship and using it to circumnavigate the globe, as a way to demonstrate the capability of hydrogen fuel cells. [131] In August 2021 the UK Government claimed it was the first to have a Hydrogen Strategy and produced a document. [132]

Western Australia's Department of Planning and Infrastructure operated three Daimler Chrysler Citaro fuel cell buses as part of its Sustainable Transport Energy for Perth Fuel Cells Bus Trial in Perth. [133] The buses were operated by Path Transit on regular Transperth public bus routes. The trial began in September 2004 and concluded in September 2007. The buses' fuel cells used a proton exchange membrane system and were supplied with raw hydrogen from a BP refinery in Kwinana, south of Perth. The hydrogen was a byproduct of the refinery's industrial process. The buses were refueled at a station in the northern Perth suburb of Malaga.

Iceland has committed to becoming the world's first hydrogen economy by the year 2050. [134] Iceland is in a unique position. Presently,[ when?] it imports all the petroleum products necessary to power its automobiles and fishing fleet. Iceland has large geothermal resources, so much that the local price of electricity actually is lower than the price of the hydrocarbons that could be used to produce that electricity.

Iceland already converts its surplus electricity into exportable goods and hydrocarbon replacements. In 2002, it produced 2,000 tons of hydrogen gas by electrolysis, primarily for the production of ammonia (NH3) for fertilizer. Ammonia is produced, transported, and used throughout the world, and 90% of the cost of ammonia is the cost of the energy to produce it.

Neither industry directly replaces hydrocarbons. Reykjavík, Iceland, had a small pilot fleet of city buses running on compressed hydrogen, [135] and research on powering the nation's fishing fleet with hydrogen is under way (for example by companies as Icelandic New Energy). For more practical purposes, Iceland might process imported oil with hydrogen to extend it, rather than to replace it altogether.

The Reykjavík buses are part of a larger program, HyFLEET:CUTE, [136] operating hydrogen fueled buses in eight European cities. HyFLEET:CUTE buses were also operated in Beijing, China and Perth, Australia (see below). A pilot project demonstrating a hydrogen economy is operational on the Norwegian island of Utsira. The installation combines wind power and hydrogen power. In periods when there is surplus wind energy, the excess power is used for generating hydrogen by electrolysis. The hydrogen is stored, and is available for power generation in periods when there is little wind.[ citation needed]

India is said to adopt hydrogen and H-CNG, due to several reasons, amongst which the fact that a national rollout of natural gas networks is already taking place and natural gas is already a major vehicle fuel. In addition, India suffers from extreme air pollution in urban areas. [137] [138]

Currently however, hydrogen energy is just at the Research, Development and Demonstration (RD&D) stage. [139] [140] As a result, the number of hydrogen stations may still be low, [141] although much more are expected to be introduced soon. [142] [143] [144]

The Turkish Ministry of Energy and Natural Resources and the United Nations Industrial Development Organization have signed a $40 million trust fund agreement in 2003 for the creation of the International Centre for Hydrogen Energy Technologies (UNIDO-ICHET) in Istanbul, which started operation in 2004. [145] A hydrogen forklift, a hydrogen cart and a mobile house powered by renewable energies are being demonstrated in UNIDO-ICHET's premises. An uninterruptible power supply system has been working since April 2009 in the headquarters of Istanbul Sea Buses company.

Another indicator of the presence of large natural gas infrastructures already in place in countries and in use by citizens is the number of natural gas vehicles present in the country. The countries with the largest amount of natural gas vehicles are (in order of magnitude): [146] Iran, China, Pakistan, Argentina, India, Brasil, Italy, Colombia, Thailand, Uzbekistan, Bolivia, Armenia, Bangladesh, Egypt, Peru, Ukraine, United States. Natural gas vehicles can also be converted to run on hydrogen.

Some hospitals have installed combined electrolyser-storage-fuel cell units for local emergency power. These are advantageous for emergency use because of their low maintenance requirement and ease of location compared to internal combustion driven generators.[ citation needed]

Also, in some private homes, fuel cell micro-CHP plants can be found, which can operate on hydrogen, or other fuels as natural gas or LPG. [147] [148] When running on natural gas, it relies on steam reforming of natural gas to convert the natural gas to hydrogen prior to use in the fuel cell. This hence still emits CO2 (see reaction) but (temporarily) running on this can be a good solution until the point where the hydrogen is starting to become distributed through the (natural gas) piping system.

In October 2021, Queensland Premier Annastacia Palaszczuk and Andrew Forrest announced that Queensland will be home to the world's largest hydrogen plant. [149]

German car manufacturer BMW has also been working with hydrogen for years[ quantify]. [150]

Partial hydrogen economy

Hydrogen is simply a method to store and transmit energy. Energy development of various alternative energy transmission and storage scenarios which begin with hydrogen production, but do not use it for all parts of the store and transmission infrastructure, may be more economic, in both near and far term. These include:

Ammonia economy

An alternative to gaseous hydrogen as an energy carrier is to bond it with nitrogen from the air to produce ammonia, which can be easily liquefied, transported, and used (directly or indirectly) as a clean and renewable fuel. [151] [152] For example, researchers at CSIRO in Australia in 2018 fuelled a Toyota Mirai and Hyundai Nexo with hydrogen separated from ammonia using a membrane technology. [30]

Hybrid heat pumps

Hybrid heat pumps (not to be confused with air water hybrids) also include a boiler which could run on methane or hydrogen, and could be a pathway to full decarbonisation of residential heating as the boiler would be used to top up the heating when the weather was very cold. [153]

Bio-SNG

As of 2019 although technically possible production of syngas from hydrogen and carbon-dioxide from bio-energy with carbon capture and storage (BECCS) via the Sabatier reaction is limited by the amount of sustainable bioenergy available: [154] therefore any bio-SNG made may be reserved for production of aviation biofuel. [155]

See also

Notes

^a Depending on the cell chemistry, specific energy of Li-ion batteries ranges between 50 and 250 Wh/kg.

References

  1. ^ "Enabling the European hydrogen economy" (PDF).
  2. ^ "Hydrogen Insights: A perspective on hydrogen investment, market development and cost competitiveness" (PDF). Hydrogen Council. February 2021. Archived (PDF) from the original on 17 February 2021. Retrieved 21 February 2021.
  3. ^ "Hydrogen isn't the fuel of the future. It's already here". World Economic Forum. Archived from the original on 2019-11-02. Retrieved 2019-11-29.
  4. ^ Deign, Jason (2019-10-14). "10 Countries Moving Toward a Green Hydrogen Economy". greentechmedia.com. Archived from the original on 2019-12-09. Retrieved 2019-11-29.
  5. ^ Prinzhofer, Alain; Tahara Cissé, Cheick Sidy; Diallo, Aliou Boubacar (October 2018). "Discovery of a large accumulation of natural hydrogen in Bourakebougou (Mali)". International Journal of Hydrogen Energy. 43 (42): 19315–19326. doi: 10.1016/j.ijhydene.2018.08.193.
  6. ^ Larin, Nikolay; Zgonnik, Viacheslav; Rodina, Svetlana; Deville, Eric; Prinzhofer, Alain; Larin, Vladimir N. (September 2015). "Natural Molecular Hydrogen Seepage Associated with Surficial, Rounded Depressions on the European Craton in Russia". Natural Resources Research. 24 (3): 369–383. doi: 10.1007/s11053-014-9257-5. S2CID  128762620.
  7. ^ Gaucher, Eric C. (1 February 2020). "New Perspectives in the Industrial Exploration for Native Hydrogen". Elements. 16 (1): 8–9. doi: 10.2138/gselements.16.1.8.
  8. ^ Truche, Laurent; Bazarkina, Elena F. (2019). "Natural hydrogen the fuel of the 21 st century". E3S Web of Conferences. 98: 03006. Bibcode: 2019E3SWC..9803006T. doi: 10.1051/e3sconf/20199803006.
  9. ^ Snyder, John (2019-09-05). "Hydrogen fuel cells gain momentum in maritime sector". Riviera Maritime Media. Archived from the original on 2021-02-08. Retrieved 2020-11-29.
  10. ^ Hannah, Ritchie. "How many people does synthetic fertilizer feed?". Our World in Data. Our World in Data. Retrieved 4 September 2021.
  11. ^ "Global Hydrogen Generation Market ize | Industry Report, 2020-2027". Archived from the original on 2019-04-16. Retrieved 2019-03-05.
  12. ^ Upham, D. Chester (17 November 2017). "Catalytic molten metals for the direct conversion of methane to hydrogen and separable non-polluting carbon in a single reaction-step commercial process (at potentially low-cost). This would provide no-pollution hydrogen from natural gas with no GHG emission, essentially forever". Science. American Association for Advancement of Science. 358 (6365): 917–921. doi: 10.1126/science.aao5023. PMID  29146810. S2CID  206663568. Retrieved 31 October 2020.
  13. ^ a b Upham, D. Chester; Agarwal, Vishal; Khechfe, Alexander; Snodgrass, Zachary R.; Gordon, Michael J.; Metiu, Horia; McFarland, Eric W. (17 November 2017). "Catalytic molten metals for the direct conversion of methane to hydrogen and separable carbon". Science. 358 (6365): 917–921. Bibcode: 2017Sci...358..917U. doi: 10.1126/science.aao5023. PMID  29146810. S2CID  206663568.
  14. ^ a b BASF. "BASF researchers working on fundamentally new, low-carbon production processes, Methane Pyrolysis". United States Sustainability. BASF. Archived from the original on 19 October 2020. Retrieved 19 October 2020.
  15. ^ UKCCC H2 2018, p. 20
  16. ^ "Hydrogen could help decarbonise the global economy". Financial Times. Archived from the original on 2019-09-17. Retrieved 2019-08-31.
  17. ^ a b IEA H2 2019, p. 13
  18. ^ IEA H2 2019, p. 18
  19. ^ National Hydrogen Association; United States Department of Energy. "The History of Hydrogen" (PDF). hydrogenassociation.org. National Hydrogen Association. p. 1. Archived from the original (PDF) on 14 July 2010. Retrieved 17 December 2010.
  20. ^ "Daedalus or Science and the Future, A paper read to the Heretics, Cambridge, on February 4th, 1923 – Transcript 1993". Archived from the original on 2017-11-15. Retrieved 2016-01-16.
  21. ^ Jones, Lawrence W (13 March 1970). Toward a liquid hydrogen fuel economy. University of Michigan Environmental Action for Survival Teach In. Ann Arbor, Michigan: University of Michigan. hdl: 2027.42/5800.
  22. ^ Bakker, Sjoerd (2010). "The car industry and the blow-out of the hydrogen hype" (PDF). Energy Policy. 38 (11): 6540–6544. doi: 10.1016/j.enpol.2010.07.019. Archived (PDF) from the original on 2018-11-03. Retrieved 2019-12-11.
  23. ^ Harrison, James. "Reactions: Hydrogen hype". Chemical Engineer. 58: 774–775. Archived from the original on 2021-02-08. Retrieved 2017-08-31.
  24. ^ Rizzi, Francesco Annunziata, Eleonora Liberati, Guglielmo Frey, Marco (2014). "Technological trajectories in the automotive industry: are hydrogen technologies still a possibility?". Journal of Cleaner Production. 66: 328–336. doi: 10.1016/j.jclepro.2013.11.069.CS1 maint: multiple names: authors list ( link)
  25. ^ Murai, Shusuke (2018-03-05). "Japan's top auto and energy firms tie up to promote development of hydrogen stations". The Japan Times Online. Japan Times. Archived from the original on 2018-04-17. Retrieved 16 April 2018.
  26. ^ Mishra, Ankit (2018-03-29). "Prospects of fuel-cell electric vehicles boosted with Chinese backing". Energy Post. Archived from the original on 2018-04-17. Retrieved 16 April 2018.
  27. ^ a b IEA H2 2019, p. 17
  28. ^ IEA H2 2019, p. 14
  29. ^ Crabtree, George W.; Dresselhaus, Mildred S.; Buchanan, Michelle V. (2004). The Hydrogen Economy (PDF) (Technical report). Archived (PDF) from the original on 2020-04-10. Retrieved 2020-03-05.
  30. ^ a b Mealey, Rachel. ”Automotive hydrogen membranes-huge breakthrough for cars" Archived 2019-06-10 at the Wayback Machine, ABC, August 8, 2018
  31. ^ "Archived copy". Argonne National Laboratory. Archived from the original on 2007-09-22. Retrieved 2007-06-15.CS1 maint: archived copy as title ( link)
  32. ^ Argonne National Laboratory. "Configuration and Technology Implications of Potential Nuclear Hydrogen System Applications" (PDF). Archived from the original (PDF) on 5 August 2013. Retrieved 29 May 2013.
  33. ^ a b "Bellona-HydrogenReport". Interstatetraveler.us. Archived from the original on 2016-06-03. Retrieved 2010-07-05.
  34. ^ a b c d BMWi (June 2020). The national hydrogen strategy (PDF). Berlin, Germany: Federal Ministry for Economic Affairs and Energy (BMWi). Archived (PDF) from the original on 2020-12-13. Retrieved 2020-11-27.
  35. ^ a b c Van de Graaf, Thijs; Overland, Indra; Scholten, Daniel; Westphal, Kirsten (December 2020). "The new oil? The geopolitics and international governance of hydrogen". Energy Research & Social Science. 70: 101667. doi: 10.1016/j.erss.2020.101667. PMC  7326412. PMID  32835007.
  36. ^ Sansom, Robert; Baxter, Jenifer; Brown, Andy; Hawksworth, Stuart; McCluskey, Ian (2020). Transitioning to hydrogen: assessing the engineering risks and uncertainties (PDF). London, United Kingdom: The Institution of Engineering and Technology (IET). Archived (PDF) from the original on 2020-05-08. Retrieved 2020-03-22.
  37. ^ Bruce, S; Temminghoff, M; Hayward, J; Schmidt, E; Munnings, C; Palfreyman, D; Hartley, P (2018). National hydrogen roadmap: pathways to an economically sustainable hydrogen industry in Australia (PDF). Australia: CSIRO. Archived (PDF) from the original on 2020-12-08. Retrieved 2020-11-28.
  38. ^ Zgonnik, Viacheslav (April 2020). "The occurrence and geoscience of natural hydrogen: A comprehensive review". Earth-Science Reviews. 203: 103140. Bibcode: 2020ESRv..20303140Z. doi: 10.1016/j.earscirev.2020.103140.
  39. ^ "Natural Hydrogen Energy LLC". Archived from the original on 2020-10-25. Retrieved 2020-09-29.
  40. ^ "Definition of Green Hydrogen" (PDF). Clean Energy Partnership. Retrieved 2014-09-06.[ permanent dead link]
  41. ^ a b Schneider, Stefan; Bajohr, Siegfried; Graf, Frank; Kolb, Thomas (October 2020). "State of the Art of Hydrogen Production via Pyrolysis of Natural Gas". ChemBioEng Reviews. 7 (5): 150–158. doi: 10.1002/cben.202000014.
  42. ^ Sampson2019-02-11T10:48:00+00:00, Joanna. "Blue hydrogen for a green future". gasworld. Archived from the original on 2019-05-09. Retrieved 2019-06-03.
  43. ^ "Brown coal the hydrogen economy stepping stone | ECT". Archived from the original on 2019-04-08. Retrieved 2019-06-03.
  44. ^ "Actual Worldwide Hydrogen Production from …". Arno A Evers. December 2008. Archived from the original on 2015-02-02. Retrieved 2008-05-09.
  45. ^ Fernandez, Sonia. "Researchers develop potentially low-cost, low-emissions technology that can convert methane without forming CO2". Phys-Org. American Institute of Physics. Archived from the original on 19 October 2020. Retrieved 19 October 2020.
  46. ^ Palmer, Clarke; Upham, D. Chester; Smart, Simon; Gordon, Michael J.; Metiu, Horia; McFarland, Eric W. (January 2020). "Dry reforming of methane catalysed by molten metal alloys". Nature Catalysis. 3 (1): 83–89. doi: 10.1038/s41929-019-0416-2. S2CID  210862772.
  47. ^ Cartwright, Jon. "The reaction that would give us clean fossil fuels forever". NewScientist. New Scientist Ltd. Archived from the original on 26 October 2020. Retrieved 30 October 2020.
  48. ^ Karlsruhe Institute of Technology. "Hydrogen from methane without CO2 emissions". Phys.Org. Phys.Org. Archived from the original on 21 October 2020. Retrieved 30 October 2020.
  49. ^ Badwal, Sukhvinder P. S.; Giddey, Sarbjit S.; Munnings, Christopher; Bhatt, Anand I.; Hollenkamp, Anthony F. (24 September 2014). "Emerging electrochemical energy conversion and storage technologies". Frontiers in Chemistry. 2: 79. Bibcode: 2014FrCh....2...79B. doi: 10.3389/fchem.2014.00079. PMC  4174133. PMID  25309898.
  50. ^ Werner Zittel; Reinhold Wurster (1996-07-08). "Chapter 3: Production of Hydrogen. Part 4: Production from electricity by means of electrolysis". HyWeb: Knowledge - Hydrogen in the Energy Sector. Ludwig-Bölkow-Systemtechnik GmbH. Archived from the original on 2007-02-07. Retrieved 2010-10-01.
  51. ^ Bjørnar Kruse; Sondre Grinna; Cato Buch (2002-02-13). "Hydrogen – Status and Possibilities". The Bellona Foundation. Archived from the original (PDF) on 2011-07-02. Efficiency factors for PEM electrolysers up to 94% are predicted, but this is only theoretical at this time.
  52. ^ "high-rate and high efficiency 3D water electrolysis". Grid-shift.com. Archived from the original on 2012-03-22. Retrieved 2011-12-13.
  53. ^ "Wide Spread Adaption of Competitive Hydrogen Solution" (PDF). nelhydrogen.com. Nel ASA. Archived (PDF) from the original on 2018-04-22. Retrieved 22 April 2018.
  54. ^ Philibert, Cédric. "Commentary: Producing industrial hydrogen from renewable energy". iea.org. International Energy Agency. Archived from the original on 22 April 2018. Retrieved 22 April 2018.
  55. ^ IEA H2 2019, p. 37
  56. ^ "How Much Electricity/Water Is Needed to Produce 1 kg of H2 by Electrolysis?". Archived from the original on 17 June 2020. Retrieved 17 June 2020.
  57. ^ https://www.hfpeurope.org/infotools/energyinfos__e/hydrogen/main03.html[ permanent dead link]
  58. ^ Tao, Yongzhen; Chen, Yang; Wu, Yongqiang; He, Yanling; Zhou, Zhihua (1 February 2007). "High hydrogen yield from a two-step process of dark- and photo-fermentation of sucrose". International Journal of Hydrogen Energy. 32 (2): 200–206. doi: 10.1016/j.ijhydene.2006.06.034. INIST: 18477081.
  59. ^ "Hydrogen production from organic solid matter". Biohydrogen.nl. Archived from the original on 2011-07-20. Retrieved 2010-07-05.
  60. ^ Hemschemeier, Anja; Melis, Anastasios; Happe, Thomas (December 2009). "Analytical approaches to photobiological hydrogen production in unicellular green algae". Photosynthesis Research. 102 (2–3): 523–540. doi: 10.1007/s11120-009-9415-5. PMC  2777220. PMID  19291418.
  61. ^ "NanoLogix generates energy on-site with bioreactor-produced hydrogen". Solid State Technology. September 20, 2007. Archived from the original on 2018-05-15. Retrieved 14 May 2018.
  62. ^ "Power from plants using microbial fuel cell" (in Dutch). Archived from the original on 2021-02-08. Retrieved 2010-07-05.
  63. ^ Janssen, H; Emonts, B.; Groehn, H. G.; Mai, H.; Reichel, R.; Stolten, D. (1 July 2001). High pressure electrolysis : the key technology for efficient H2 production (PDF). Hypothesis IV: Hydrogen power - theoretical and engineering solutions international symposium.[ permanent dead link]
  64. ^ Carmo, M; Fritz D; Mergel J; Stolten D (2013). "A comprehensive review on PEM water electrolysis". Journal of Hydrogen Energy. 38 (12): 4901–4934. doi: 10.1016/j.ijhydene.2013.01.151.
  65. ^ "2003-PHOEBUS-Pag.9" (PDF). Archived from the original (PDF) on 2009-03-27. Retrieved 2010-07-05.
  66. ^ "Finland exporting TEN-T fuel stations". December 2015. Archived from the original on 2016-08-28. Retrieved 2016-08-22.
  67. ^ "Steam heat: researchers gear up for full-scale hydrogen plant" (Press release). Science Daily. 2008-09-18. Archived from the original on 2008-09-21. Retrieved 2008-09-19.
  68. ^ "Nuclear Hydrogen R&D Plan" (PDF). U.S. Dept. of Energy. March 2004. Archived from the original (PDF) on 2008-05-18. Retrieved 2008-05-09.
  69. ^ Valenti, Giovanni; Boni, Alessandro; Melchionna, Michele; Cargnello, Matteo; Nasi, Lucia; Bertoni, Giovanni; Gorte, Raymond J.; Marcaccio, Massimo; Rapino, Stefania; Bonchio, Marcella; Fornasiero, Paolo; Prato, Maurizio; Paolucci, Francesco (December 2016). "Co-axial heterostructures integrating palladium/titanium dioxide with carbon nanotubes for efficient electrocatalytic hydrogen evolution". Nature Communications. 7 (1): 13549. Bibcode: 2016NatCo...713549V. doi: 10.1038/ncomms13549. PMC  5159813. PMID  27941752.
  70. ^ William Ayers, US Patent 4,466,869 Photolytic Production of Hydrogen
  71. ^ Navarro Yerga, Rufino M.; Álvarez Galván, M. Consuelo; del Valle, F.; Villoria de la Mano, José A.; Fierro, José L. G. (22 June 2009). "Water Splitting on Semiconductor Catalysts under Visible-Light Irradiation". ChemSusChem. 2 (6): 471–485. doi: 10.1002/cssc.200900018. PMID  19536754.
  72. ^ Navarro, R.M.; Del Valle, F.; Villoria de la Mano, J.A.; Álvarez-Galván, M.C.; Fierro, J.L.G. (2009). "Photocatalytic Water Splitting Under Visible Light". Advances in Chemical Engineering - Photocatalytic Technologies. Advances in Chemical Engineering. 36. pp. 111–143. doi: 10.1016/S0065-2377(09)00404-9. ISBN  978-0-12-374763-1.
  73. ^ Nann, Thomas; Ibrahim, Saad K.; Woi, Pei-Meng; Xu, Shu; Ziegler, Jan; Pickett, Christopher J. (22 February 2010). "Water Splitting by Visible Light: A Nanophotocathode for Hydrogen Production". Angewandte Chemie International Edition. 49 (9): 1574–1577. doi: 10.1002/anie.200906262. PMID  20140925.
  74. ^ Yamamura, Tetsushi (August 2, 2015). "Panasonic moves closer to home energy self-sufficiency with fuel cells". Asahi Shimbun. Archived from the original on August 7, 2015. Retrieved 2015-08-02.
  75. ^ "DLR Portal - DLR scientists achieve solar hydrogen production in a 100-kilowatt pilot plant". Dlr.de. 2008-11-25. Archived from the original on 2013-06-22. Retrieved 2009-09-19.
  76. ^ "353 Thermochemical cycles" (PDF). Archived (PDF) from the original on 2009-02-05. Retrieved 2010-07-05.
  77. ^ UNLV Thermochemical cycle automated scoring database (public)[ permanent dead link]
  78. ^ "Development of Solar-powered Thermochemical Production of Hydrogen from Water" (PDF). Archived (PDF) from the original on 2007-04-17. Retrieved 2010-07-05.
  79. ^ Jie, Xiangyu; Li, Weisong; Slocombe, Daniel; Gao, Yige; Banerjee, Ira; Gonzalez-Cortes, Sergio; Yao, Benzhen; AlMegren, Hamid; Alshihri, Saeed; Dilworth, Jonathan; Thomas, John; Xiao, Tiancun; Edwards, Peter (2020). "Microwave-initiated catalytic deconstruction of plastic waste into hydrogen and high-value carbons". Nature Catalysis. 3 (11): 902–912. doi: 10.1038/s41929-020-00518-5. ISSN  2520-1158. S2CID  222299492.
  80. ^ http://www.nedstack.com/images/stories/news/documents/20120202_Press%20release%20Solvay%20PEM%20Power%20Plant%20start%20up.pdf Archived 2014-12-08 at the Wayback Machine Nedstack
  81. ^ "Different Gases from Steel Production Processes". Archived from the original on 27 March 2016. Retrieved 5 July 2020.
  82. ^ "Production of Liquefied Hydrogen Sourced by COG" (PDF). Archived (PDF) from the original on 8 February 2021. Retrieved 8 July 2020.
  83. ^ Zubrin, Robert (2007). Energy Victory. Amherst, New York: Prometheus Books. pp.  117–118. ISBN  978-1-59102-591-7. The situation is much worse than this, however, because before the hydrogen can be transported anywhere, it needs to be either compressed or liquefied. To liquefy it, it must be refrigerated down to a temperature of -253°C (20 degrees above absolute zero). At these temperatures, fundamental laws of thermodynamics make refrigerators extremely inefficient. As a result, about 40 percent of the energy in the hydrogen must be spent to liquefy it. This reduces the actual net energy content of our product fuel to 792 kcal. In addition, because it is a cryogenic liquid, still more energy could be expected to be lost as the hydrogen boils away as it is warmed by heat leaking in from the outside environment during transport and storage.
  84. ^ Savvides, Nick (2017-01-11). "Japan plans to use imported liquefied hydrogen to fuel Tokyo 2020 Olympics". Safety At Sea. IHS Markit Maritime Portal. Archived from the original on 2018-04-23. Retrieved 22 April 2018.
  85. ^ S.Sadaghiani, Mirhadi (2 March 2017). "Introducing and energy analysis of a novel cryogenic hydrogen liquefaction process configuration". International Journal of Hydrogen Energy. 42 (9).
  86. ^ 1994 – ECN abstract Archived 2004-01-02 at the Wayback Machine. Hyweb.de. Retrieved on 2012-01-08.
  87. ^ European Renewable Energy Network Archived 2019-07-17 at the Wayback Machine pp. 86, 188
  88. ^ "Energy storage – the role of electricity" (PDF). European Commission. European Commission. Archived from the original (PDF) on 8 November 2020. Retrieved 22 April 2018.
  89. ^ "Hyunder". Archived from the original on 2013-11-11. Retrieved 2013-11-11.
  90. ^ Storing renewable energy: Is hydrogen a viable solution?[ permanent dead link]
  91. ^ "BRINGING NORTH SEA ENERGY ASHORE EFFICIENTLY" (PDF). worldenergy.org. World Energy Council Netherlands. Archived (PDF) from the original on 23 April 2018. Retrieved 22 April 2018.
  92. ^ GERDES, JUSTIN (2018-04-10). "Enlisting Abandoned Oil and Gas Wells as 'Electron Reserves'". greentechmedia.com. Wood MacKenzie. Archived from the original on 2018-04-23. Retrieved 22 April 2018.
  93. ^ Anscombe, Nadya (4 June 2012). "Energy storage: Could hydrogen be the answer?". Solar Novus Today. Archived from the original on 19 August 2013. Retrieved 3 November 2012.
  94. ^ Naturalhy Archived 2012-01-18 at the Wayback Machine
  95. ^ Kijk magazine, 10, 2019
  96. ^ 50% hydrogen for Europe. A manifesto by Frank Wouters and Ad van Wijk
  97. ^ Bhadhesia, Harry. "Prevention of Hydrogen Embrittlement in Steels" (PDF). Phase Transformations & Complex Properties Research Group, Cambridge University. Archived (PDF) from the original on 11 November 2020. Retrieved 17 December 2020.
  98. ^ IEA H2 2019, p. 15
  99. ^ "Japan's Hydrogen Strategy and Its Economic and Geopolitical Implications". Etudes de l'Ifri. Archived from the original on 10 February 2019. Retrieved 9 February 2019.
  100. ^ "South Korea's Hydrogen Economy Ambitions". The Diplomat. Archived from the original on 9 February 2019. Retrieved 9 February 2019.
  101. ^ "The world's largest-class hydrogen production, Fukushima Hydrogen Energy Research Field (FH2R) now is completed at Namie town in Fukushima". Toshiba Energy Press Releases. Toshiba Energy Systems and Solutions Corporations. 7 March 2020. Archived from the original on 22 April 2020. Retrieved 1 April 2020.
  102. ^ Timmer, John (2021-08-05). "The hydrogen economy is about to get weird". Ars Technica. Retrieved 2021-10-08.
  103. ^ Editor (2019-06-14). "Hydrogen could replace natural gas to heat homes and slash carbon emissions, new report claims | Envirotec". Archived from the original on 2019-09-25. Retrieved 2019-09-25.CS1 maint: extra text: authors list ( link)
  104. ^ Murray, Jessica (2020-01-24). "Zero-carbon hydrogen injected into gas grid for first time in groundbreaking UK trial". The Guardian. ISSN  0261-3077. Archived from the original on 2020-01-24. Retrieved 2020-01-24.
  105. ^ frankwouters1 (2019-05-07). "A European Hydrogen Manifesto". Frank Wouters. Archived from the original on 2020-09-20. Retrieved 2019-12-02.
  106. ^ "idealhy.eu - Liquid Hydrogen Outline". idealhy.eu. Archived from the original on 2020-11-11. Retrieved 2019-12-02.
  107. ^ "Power-to-weight ratio". .eere.energy.gov. 2009-06-23. Archived from the original on 2010-06-09. Retrieved 2010-07-05.
  108. ^ "EPA mileage estimates". Honda FCX Clarity - Vehicle Specifications. American Honda Motor Company. Archived from the original on 1 July 2013. Retrieved 17 December 2010.
  109. ^ "Fuel Cell Technologies Office; Accomplishments and Progress". US Department of Energy. Archived from the original on 15 April 2018. Retrieved 16 April 2018.
  110. ^ "This company may have solved one of the hardest problems in clean energy". Vox. 2018-02-16. Archived from the original on 2019-11-12. Retrieved 9 February 2019.
  111. ^ Utgikar, Vivek P; Thiesen, Todd (2005). "Safety of compressed hydrogen fuel tanks: Leakage from stationary vehicles". Technology in Society. 27 (3): 315–320. doi: 10.1016/j.techsoc.2005.04.005.
  112. ^ "Hydrogen Sensor: Fast, Sensitive, Reliable, and Inexpensive to Produce" (PDF). Argonne National Laboratory. September 2006. Archived from the original (PDF) on 2013-07-01. Retrieved 2008-05-09.
  113. ^ "Canadian Hydrogen Safety Program testing H2/CNG". Hydrogenandfuelcellsafety.info. Archived from the original on 2011-07-21. Retrieved 2010-07-05.
  114. ^ a b "Transitioning to hydrogen: Assessing the engineering risks and uncertainties". theiet.org. Archived from the original on 2020-06-19. Retrieved 2020-04-11.
  115. ^ UKCCC H2 2018, p. 113
  116. ^ a b "A wake-up call on green hydrogen: the amount of wind and solar needed is immense | Recharge". Recharge | Latest renewable energy news. Archived from the original on 2020-04-11. Retrieved 2020-04-11.
  117. ^ UKCCC H2 2018, p. 7
  118. ^ UKCCC H2 2018, p. 124
  119. ^ UKCCC H2 2018, p. 118
  120. ^ "Australia's pathway to $2 per kg hydrogen - ARENAWIRE". Australian Renewable Energy Agency. Archived from the original on 2020-12-15. Retrieved 2021-01-06.
  121. ^ Ambrose, Jillian (20 August 2021). "Oil firms made 'false claims' on blue hydrogen costs, says ex-lobby boss". The Guardian. London, United Kingdom. ISSN  0261-3077. Retrieved 2021-08-24.
  122. ^ "Are hydrogen fuel cell vehicles the future of autos?". ABC News. Archived from the original on 2021-01-17. Retrieved 2021-01-18.
  123. ^ Siddiqui, Faiz. "The plug-in electric car is having its moment. But despite false starts, Toyota is still trying to make the fuel cell happen". Washington Post. ISSN  0190-8286. Archived from the original on 2021-01-19. Retrieved 2021-01-18.
  124. ^ "Experimental 'wind to hydrogen' system up and running". Physorg.com. January 8, 2007. Archived from the original on 2013-07-01. Retrieved 2008-05-09.
  125. ^ "Hydrogen Engine Center Receives Order for Hydrogen Power Generator 250kW Generator for Wind/Hydrogen Demonstration" (PDF). Hydrogen Engine Center, Inc. May 16, 2006. Archived from the original (PDF) on May 27, 2008. Retrieved 2008-05-09.
  126. ^ "Stuart Island Energy Initiative". Archived from the original on 2013-07-01. Retrieved 2008-05-09.
  127. ^ a b "Hydrogen transport & distribution". Archived from the original on 2019-09-29. Retrieved 2019-09-29.
  128. ^ "Archived copy". Archived from the original on 2020-08-07. Retrieved 2020-08-14.CS1 maint: archived copy as title ( link)
  129. ^ "ECHA". Archived from the original on 2020-08-12. Retrieved 2020-08-14.
  130. ^ "Hydrogen buses". Transport for London. Archived from the original on March 23, 2008. Retrieved 2008-05-09.
  131. ^ "The Hydrogen Expedition" (PDF). January 2005. Archived from the original (PDF) on 2008-05-27. Retrieved 2008-05-09.
  132. ^ "UK Hydrogen Strategy" (PDF). UK Government. August 2021.
  133. ^ "Perth Fuel Cell Bus Trial". Department for Planning and Infrastructure, Government of Western Australia. 13 April 2007. Archived from the original on 7 June 2008. Retrieved 2008-05-09.
  134. ^ Hannesson, Hjálmar W. (2007-08-02). "Climate change as a global challenge". Iceland Ministry for Foreign Affairs. Archived from the original on 2013-07-01. Retrieved 2008-05-09.
  135. ^ Doyle, Alister (January 14, 2005). "Iceland's hydrogen buses zip toward oil-free economy". Reuters. Archived from the original on July 24, 2012. Retrieved 2008-05-09.
  136. ^ "What is HyFLEET:CUTE?". Archived from the original on 2008-02-24. Retrieved 2008-05-09.
  137. ^ "Hydrogen vehicles and refueling infrastructure in India" (PDF). Archived (PDF) from the original on 2017-06-12. Retrieved 2019-09-28.
  138. ^ Das, L (1991). "Exhaust emission characterization of hydrogen-operated engine system: Nature of pollutants and their control techniques". International Journal of Hydrogen Energy. 16 (11): 765–775. doi: 10.1016/0360-3199(91)90075-T.
  139. ^ "MNRE: FAQ". Archived from the original on 2019-09-21. Retrieved 2019-09-28.
  140. ^ Overview of Indian Hydrogen Programme
  141. ^ "H2 stations worldwide". Archived from the original on 2019-09-21. Retrieved 2019-09-28.
  142. ^ "India working on more H2 stations". Archived from the original on 2019-09-21. Retrieved 2019-09-28.
  143. ^ "Shell plans to open 1200 fuel stations in India, some of which may include H2 refilling". Archived from the original on 2019-09-22. Retrieved 2019-09-28.
  144. ^ "Hydrogen Vehicles and Refueling Infrastructure in India" (PDF). Archived (PDF) from the original on 2017-06-12. Retrieved 2019-09-28.
  145. ^ "Independent Mid-Term Review of the UNIDO Project: Establishment and operation of the International Centre for Hydrogen Energy Technologies (ICHET), TF/INT/03/002" (PDF). UNIDO. 31 August 2009. Archived from the original (PDF) on 1 June 2010. Retrieved 20 July 2010.
  146. ^ "Worldwide NGV statistics". Archived from the original on 2015-02-06. Retrieved 2019-09-29.
  147. ^ "Fuel Cell micro CHP". Archived from the original on 2019-11-06. Retrieved 2019-10-23.
  148. ^ "Fuel cell micro Cogeneration". Archived from the original on 2019-10-23. Retrieved 2019-10-23.
  149. ^ https://www.abc.net.au/news/2021-10-11/queensland-hydrogen-twiggy-forrest-ammonia-feasiblity/100528732
  150. ^ https://www.scmp.com/article/612717/test-drive-bmws-car-future-its-gas
  151. ^ Agosta, Vito (July 10, 2003). "The Ammonia Economy". Archived from the original on May 13, 2008. Retrieved 2008-05-09.
  152. ^ "Renewable Energy". Iowa Energy Center. Archived from the original on 2008-05-13. Retrieved 2008-05-09.
  153. ^ UKCCC H2 2018, p. 36: "Near-term pursuit of hybrid heat pumps would not necessarily lead to a long-term solution of hybrid heat pumps with hydrogen boilers."
  154. ^ UKCCC H2 2018, p. 79: The potential for bio-gasification with CCS to be deployed at scale is limited by the amount of sustainable bioenergy available. .... "
  155. ^ UKCCC H2 2018, p. 33: production of biofuels, even with CCS, is only one of the best uses of the finite sustainable bio-resource if the fossil fuels it displaces cannot otherwise feasibly be displaced (e.g. use of biomass to produce aviation biofuels with CCS)."

Sources

External links